所有图片(2)
About This Item
线性分子式:
[(C6H5)2PC10H6-]2
CAS号:
分子量:
622.67
Beilstein:
5321443
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
solid
旋光性
[α]19/D −233°, c = 0.3 in toluene
光学纯度
ee: 99% (HPLC)
mp
238-240 °C (lit.)
官能团
phosphine
SMILES字符串
P(c8ccccc8)(c7ccccc7)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5ccccc5)c4ccccc4)cccc3
InChI
1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI key
MUALRAIOVNYAIW-UHFFFAOYSA-N
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应用
2,2′-双(二苯基膦)-1,1′-联萘及其铑和钌衍生物可作为高选择性均相催化剂，用于芳基酮、β-酮酸酯和 α-氨基酮的还原反应。也可用于烯烃的不对称氢化和氢甲酰化反应、不对称 Heck 反应和烯丙基的不对称异构化反应。
用于钯催化不对称串联 Heck 反应的配体，这种碳负离子捕获过程可合成三环倍半萜烯。也可用于钌催化的 α,β-不饱和酸的不对称氢化反应。
用于钯催化不对称串联 Heck 反应的配体，这种碳负离子捕获过程可合成三环倍半萜烯。也可用于钌催化的 α,β-不饱和酸的不对称氢化反应。
作为以下过程的反应物：
- 对映选择性和非对映选择性非极化羰基烯丙基化
- 合成有机膦氧化物，作为抗肿瘤药
- 羟基的SN2卤化
- 合成BINAP配合物
- BINAP螯合物的构象灵活性研究
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Leslie Ann So Alfaro et al.
Stem cells (Dayton, Ohio), 29(12), 2030-2041 (2011-10-15)
Expression of the cell surface sialomucin CD34 is common to many adult stem cell types, including muscle satellite cells. However, no clear stem cell or regeneration-related phenotype has ever been reported in mice lacking CD34, and its function on these
Synlett, 3053-3053 (2006)
Susana Aguilar et al.
PloS one, 4(11), e8013-e8013 (2009-12-04)
Many common diseases of the gas exchange surface of the lung have no specific treatment but cause serious morbidity and mortality. Idiopathic Pulmonary Fibrosis (IPF) is characterized by alveolar epithelial cell injury, interstitial inflammation, fibroblast proliferation and collagen accumulation within
David M Tellers et al.
Journal of the American Chemical Society, 128(51), 17063-17073 (2006-12-21)
Ruthenium complexes employing axially chiral ligands were found to be effective asymmetric hydrogenation catalysts for the reduction of alpha,beta-unsaturated ene acid 1-E to give 2, a prostaglandin D2 (PGD2) receptor antagonist. With [(S-BINAP)Ru(p-cymene)Cl2]2 (3, S-BINAP = (S)-(+)-2,2'-bis(diphenylphospino)-1,1'-binapthyl), it was discovered
Leandro Z Agudelo et al.
Nature communications, 10(1), 2767-2767 (2019-06-27)
The coactivator PGC-1α1 is activated by exercise training in skeletal muscle and promotes fatigue-resistance. In exercised muscle, PGC-1α1 enhances the expression of kynurenine aminotransferases (Kats), which convert kynurenine into kynurenic acid. This reduces kynurenine-associated neurotoxicity and generates glutamate as a
商品
We present an article concerning BINAP/SEGPHOS® Ligands and Complexes.
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