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Merck
CN

29580

Sigma-Aldrich

顺,顺-1,5-环辛二烯

≥98.0% (GC)

别名:

COD

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About This Item

经验公式(希尔记法):
C8H12
CAS号:
分子量:
108.18
Beilstein:
1209288
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

≥98.0% (GC)

折射率

n20/D 1.493

溶解性

water: soluble 0.05 g/L

密度

0.880 g/mL at 20 °C (lit.)

SMILES字符串

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

InChI key

VYXHVRARDIDEHS-QGTKBVGQSA-N

一般描述

使用开环易位聚合反应,在气相中探索了低应变能的顺式,顺式-1,5-环辛二烯(环烯烃)的表面接枝。通过质子核磁共振谱研究了顺式,顺式-1,5-环辛二烯与 β-环糊精(β-CD)的包合物

应用

顺式,顺式-1,5-环辛二烯(COD)已作为配体用于以下反应中:
  • Z)-1,2-二卤代烯烃的区域和立体选择性合成过程
  • 制备金属络合物的过程,例如 bis-COD-镍,一种用于制备(PI)-烯丙基卤化镍的多功能试剂

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

89.6 °F - closed cup

闪点(°C)

32 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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