295183
环丙烷
≥99%
别名:
Trimethylene (6CI)
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关于此项目
经验公式（希尔记法）:
C3H6
化学文摘社编号:
分子量:
42.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12142100
EC Number:
200-847-8
MDL number:
Assay:
≥99%
InChI key
LVZWSLJZHVFIQJ-UHFFFAOYSA-N
InChI
1S/C3H6/c1-2-3-1/h1-3H2
SMILES string
C1CC1
vapor density
1.45 (vs air)
assay
≥99%
autoignition temp.
928 °F
expl. lim.
10.4 %
bp
−33 °C (lit.)
mp
−128 °C (lit.)
Quality Level
Application
Cyclopropane has been used as the pseudo-π unsaturated hydrocarbon prototype to study the rotational spectrum of its complex formed with chlorine monofluoride and the similarity of this complex with isotopomers.
Packaging
Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Gas 1 - Press. Gas Liquefied gas
存储类别
2A - Gases
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Shuhei Kawamura et al.
Journal of medicinal chemistry, 56(9), 3689-3700 (2013-04-04)
The natural product belactosin A (1) with a trans-cyclopropane structure is a useful prototype compound for developing potent proteasome (core particle, CP) inhibitors. To date, 1 and its analogues are the only CP ligands that bind to both the nonprimed
Pedro S Coelho et al.
Science (New York, N.Y.), 339(6117), 307-310 (2012-12-22)
Transition metal-catalyzed transfers of carbenes, nitrenes, and oxenes are powerful methods for functionalizing C=C and C-H bonds. Nature has evolved a diverse toolbox for oxene transfers, as exemplified by the myriad monooxygenation reactions catalyzed by cytochrome P450 enzymes. The isoelectronic
Timothy R Newhouse et al.
Organic letters, 15(7), 1591-1593 (2013-03-09)
A highly effective acid-catalyzed cyclopropyl ester to γ-lactone skeletal rearrangement has been demonstrated and applied to the synthesis of a variety of bi- and tricyclic functionalized lactones, rigid and highly compact structures for use as biological probes.
Yoshihiro Oonishi et al.
Angewandte Chemie (International ed. in English), 51(29), 7305-7308 (2012-06-29)
Giving direction: An C sp 3-H bond activation directed by a rhodacycle intermediate has been found to occur in a Rh(I)-catalyzed reaction between an allene moiety having a tert-butyl substituent, and tethered alkynes. Cyclic compounds containing a cyclopropane ring were obtained in
Thomas Schalck et al.
Microorganisms, 9(2) (2021-02-04)
Fuels and polymer precursors are widely used in daily life and in many industrial processes. Although these compounds are mainly derived from petrol, bacteria and yeast can produce them in an environment-friendly way. However, these molecules exhibit toxic solvent properties
商品
Solvias MeOBIPHEP Ligands: State-of-the-art atropisomeric MeOBIPHEP ligands, also referred to as MeO-BIPHEP, originally developed by Roche, have an extraordinarily broad performance profile for many synthetic applications due to their modular ligand design.
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