29510
(R)-(+)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
≥97%, optical purity ee: ≥99%
别名:
(R)-(+)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯, (R)-(+)-MeO-BIPHEP, SL-A101-1
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C38H32O2P2
化学文摘社编号:
分子量:
582.61
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4790083
产品名称
(R)-(+)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦), ≥97%, optical purity ee: ≥99%
SMILES string
COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
InChI
1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
assay
≥97%
optical purity
ee: ≥99%
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
functional group
phosphine
greener alternative category
Quality Level
正在寻找类似产品? 访问 产品对比指南
General description
与 Solvias AG 联合销售
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product is a Biobased products, showing key improvements in Green Chemistry Principles “Less Hazardous Chemical Syntheses” and “Use of Renewable Feedstock”.
Application
Atropisomeric MeOBIPHEP ligands
- Hydrogenation of α- and β-functionalized ketones
- Hydrogenation of heteroarenes
- C–C coupling reactions
Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines; the Ru(II) complex hydrogenates ß-keto esters in high enantioselectivity; the Pd(0) complex for cyclization of hydroxy allylic carbonates.
Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
R. Schmid et al.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 68, 131-138 (1996)
V. Blandin et al.
European Journal of Organic Chemistry, 1787-1787 (1999)
R. Schmid et al.
Helvetica Chimica Acta, 74, 370-370 (1991)
B. Heiser et al.
Tetrahedron Asymmetry, 2, 51-51 (1991)
J.R. Labrosse et al.
Tetrahedron Asymmetry, 10, 1069-1069 (1999)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持