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质量水平
方案
≥97%
光学纯度
ee: ≥99%
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
官能团
phosphine
环保替代产品分类
SMILES字符串
COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI
1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
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一般描述
与 Solvias AG 联合销售
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product is a Biobased products, showing key improvements in Green Chemistry Principles “Less Hazardous Chemical Syntheses” and “Use of Renewable Feedstock”.
应用
Atropisomeric MeOBIPHEP ligands
- Hydrogenation of α- and β-functionalized ketones
- Hydrogenation of heteroarenes
- C–C coupling reactions
Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines; the Ru(II) complex hydrogenates ß-keto esters in high enantioselectivity; the Pd(0) complex for cyclization of hydroxy allylic carbonates.
Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
R. Schmid et al.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 68, 131-138 (1996)
V. Blandin et al.
European Journal of Organic Chemistry, 1787-1787 (1999)
R. Schmid et al.
Helvetica Chimica Acta, 74, 370-370 (1991)
B. Heiser et al.
Tetrahedron Asymmetry, 2, 51-51 (1991)
J.R. Labrosse et al.
Tetrahedron Asymmetry, 10, 1069-1069 (1999)
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