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Merck
CN

295019

Sigma-Aldrich

三氯化硼

99.9%

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About This Item

经验公式(希尔记法):
BCl3
CAS号:
分子量:
117.17
EC 号:
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:

蒸汽密度

4.05 (vs air)

质量水平

蒸汽压

1128 mmHg ( 20 °C)
2815 mmHg ( 55 °C)

方案

99.9%

反应适用性

reagent type: catalyst
core: boron

沸点

12.5 °C (lit.)

mp

−107 °C (lit.)

SMILES字符串

ClB(Cl)Cl

InChI

1S/BCl3/c2-1(3)4

InChI key

FAQYAMRNWDIXMY-UHFFFAOYSA-N

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应用

用于具有 p 型半导体性质的层状类石墨材料的高温合成。衍生自 BCl3 的高度酸性硼酸氧化铝,可提高 Diels-Alder 反应的区域选择性和非对映立体选择性。

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推荐使用 Monel 控制阀 Z146978 或 Monel 气流阀 Z562483。

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

储存分类代码

2A - Gases

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
Warwick J Belcher et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 1602-1614 (2008-03-13)
The reactions of boron halides with free base porphyrins under conditions where partial hydrolysis of the boron halides can occur give diboron porphyrin complexes containing BOB moieties in which each boron is bonded to two porphyrin nitrogen atoms. BF(3).OEt(2) with
C Matthäus et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 521-534 (2001-04-13)
A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibrational modes
Dean Marković et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(20), 5969-5975 (2010-04-17)
The first ene reactions of SO(2) and unfunctionalized alkenes are reported. Calculations suggest that the endergonic ene reactions of SO(2) with alkenes can be used to generate beta,gamma-unsaturated sulfinyl and sulfonyl compounds. Indeed, in the presence of one equivalent of

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