295019
三氯化硼
99.9%
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关于此项目
经验公式（希尔记法）:
BCl3
化学文摘社编号:
分子量:
117.17
UNSPSC Code:
12352106
PubChem Substance ID:
EC Number:
233-658-4
MDL number:
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
InChI
1S/BCl3/c2-1(3)4
SMILES string
ClB(Cl)Cl
vapor density
4.05 (vs air)
vapor pressure
1128 mmHg ( 20 °C), 2815 mmHg ( 55 °C)
assay
99.9%
reaction suitability
reagent type: catalyst
core: boron
bp
12.5 °C (lit.)
mp
−107 °C (lit.)
Quality Level
Application
用于具有 p 型半导体性质的层状类石墨材料的高温合成。衍生自 BCl3 的高度酸性硼酸氧化铝，可提高 Diels-Alder 反应的区域选择性和非对映立体选择性。
Other Notes
推荐使用 Monel 控制阀 Z146978 或 Monel 气流阀 Z562483。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
2A - Gases
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
C Matthäus et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 521-534 (2001-04-13)
A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibrational modes
Warwick J Belcher et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 1602-1614 (2008-03-13)
The reactions of boron halides with free base porphyrins under conditions where partial hydrolysis of the boron halides can occur give diboron porphyrin complexes containing BOB moieties in which each boron is bonded to two porphyrin nitrogen atoms. BF(3).OEt(2) with
Guillaume Reinisch et al.
The journal of physical chemistry. A, 115(18), 4786-4797 (2011-04-16)
We report on a theoretical study of the gas-phase decomposition of boron trichloride in the presence of hydrogen radicals using ab initio energetic calculations coupled to TST, RRKM, and VTST-VRC kinetic calculations. In particular, we present an addition-elimination mechanism (BCl(3)
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