推荐产品
应用
用于具有 p 型半导体性质的层状类石墨材料的高温合成。衍生自 BCl3 的高度酸性硼酸氧化铝，可提高 Diels-Alder 反应的区域选择性和非对映立体选择性。
推荐产品
推荐使用 Monel 控制阀 Z146978 或 Monel 气流阀 Z562483。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
2A - Gases
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)
法规信息
新产品
McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
Novel polyhydroxylated cyclic nitrones and N-hydroxypyrrolidines through BCl3-mediated deprotection.
Stéphanie Desvergnes et al.
Organic letters, 10(14), 2967-2970 (2008-06-24)
A general method to prepare a new class of carbohydrate-derived, enantiomerically pure polyhydroxypyrroline N-oxides from their alkoxy (protected) derivatives is presented. Boron trichloride is shown to cleave efficiently benzyl ethers and ketals without affecting the imine N-oxide functionality of nitrones.
Lei Zhang et al.
Journal of combinatorial chemistry, 8(3), 361-367 (2006-05-09)
A novel and efficient microwave-assisted, BCl(3) mediated coupling reaction to synthesize o-(hydroxyaryl)(aryl)methanone structures from phenols and acyl chlorides is described. This reaction was further incorporated into a two-step synthesis of biologically interesting xanthones.
Stephen Sproules et al.
Inorganic chemistry, 50(10), 4503-4514 (2011-04-19)
Sky-blue Tp*WOCl(2) has been synthesized from the high-yielding reaction of Tp*WO(2)Cl with boron trichloride in refluxing toluene. Dark-red Tp*WOI(2) was prepared via thermal decarbonylation followed by aerial oxidation of Tp*WI(CO)(3) in acetonitrile. From these precursors, an extensive series of mononuclear
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