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Merck
CN

294985

Sigma-Aldrich

丙二烯

≥95%

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别名:
Propadiene
线性分子式:
H2C=C=CH2
CAS号:
分子量:
40.06
Beilstein:
1730774
EC 号:
MDL编号:
UNSPSC代码:
12142100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

1.42 (20 °C, vs air)

质量水平

蒸汽压

6795 mmHg ( 21 °C)

检测方案

≥95%

expl. lim.

13 %

bp

−34 °C (lit.)

mp

−136 °C (lit.)

SMILES字符串

C=C=C

InChI

1S/C3H4/c1-3-2/h1-2H2

InChI key

IYABWNGZIDDRAK-UHFFFAOYSA-N

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应用

  • 丙二烯广泛用于各种光化学、 和过渡金属介导的环加成反应。
  • 它可以锂化产生丙二烯锂,后者与烷基卤化物反应产生末端丙二烯。
  • 附加应用包括分别通过与甲锡烷基铜酸盐和甲硅烷基铜酸盐反应制备异丙烯基硅烷和异丙烯基锡烷等试剂。

包装

以配备CGA180M/CGA110F针阀的碳钢气阀瓶供货。

兼容以下设备:
  • Aldrich® 气阀瓶站系统
  • Aldrich®气阀瓶气体调节器

其他说明

法律信息

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

吹扫阀

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价格

软管倒钩

产品编号
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象形图

FlameGas cylinder

警示用语:

Danger

危险声明

危险分类

Flam. Gas 1 - Press. Gas Liquefied gas

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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?-Cyanocyclobutenone as a highly reactive dienophile in comparison to ?-cyanocyclopentenone.
Bienfait B, et al.
Tetrahedron, 47(38), 8167-8176 (1991)
Chenggang Liu et al.
Plant physiology, 165(4), 1424-1439 (2014-06-21)
In Arabidopsis (Arabidopsis thaliana), the major MYB protein regulating proanthocyanidin (PA) biosynthesis is TT2, named for the transparent testa phenotype of tt2 mutant seeds that lack PAs in their coats. In contrast, the MYB5 transcription factor mainly regulates seed mucilage
The silyl-cupration and stannyl-cupration of allenes.
Fleming I, et al.
Tetrahedron, 45(2), 413-424 (1989)
Takuya Hashimoto et al.
Nature chemistry, 5(3), 240-244 (2013-02-21)
Allenes are molecules based on three carbons connected by two cumulated carbon-carbon double bonds. Given their axially chiral nature and unique reactivity, substituted allenes have a variety of applications in organic chemistry as key synthetic intermediates and directly as part
David Tejedor et al.
Chemical Society reviews, 42(2), 458-471 (2012-10-05)
The propargyl Claisen rearrangement is a known protocol to gain access to functionalized allenes through the [3,3]-sigmatropic transformation of propargyl vinyl ethers. The correct use of appropriate propargyl vinyl ethers as starting materials coupled with suitable reaction conditions can aid

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