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方案
97%
折射率
n20/D 1.5632 (lit.)
沸点
113-114 °C/18 mmHg (lit.)
密度
1.047 g/mL at 25 °C (lit.)
官能团
ether
thioether
SMILES字符串
COCSc1ccccc1
InChI
1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3
InChI key
QPXQVNXSQCRWEV-UHFFFAOYSA-N
一般描述
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.
应用
Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
203.0 °F - closed cup
闪点(°C)
95 °C - closed cup
个人防护装备
Eyeshields, Gloves
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.
Maricich TJ and Harrington CK.
Journal of the American Chemical Society, 94(14), 5115-5116 (1972)
S P Hanlon et al.
Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)
The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic
Solvent free permanganate oxidations.
Shaabani A and Lee DG.
Tetrahedron Letters, 42(34), 5833-5836 (2001)
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