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Merck
CN

29383

三氟甲磺酸三甲基硅酯

Wacker Chemie AG, ≥98.0% (T)

别名:

硅烷 TMS-三氟甲磺酸酯, TMS 三氟甲基磺酸酯, TMSOTf, 三甲基硅基三氟甲烷磺酸酯

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关于此项目

线性分子式:
CF3SO3Si(CH3)3
化学文摘社编号:
分子量:
222.26
EC Number:
248-565-4
UNSPSC Code:
12352103
PubChem Substance ID:
Beilstein/REAXYS Number:
1868911
MDL number:
Assay:
≥98.0% (T)
Form:
liquid
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InChI

1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3

InChI key

FTVLMFQEYACZNP-UHFFFAOYSA-N

SMILES string

C[Si](C)(C)OS(=O)(=O)C(F)(F)F

assay

≥98.0% (T)

form

liquid

manufacturer/tradename

Wacker Chemie AG

refractive index

n20/D 1.36 (lit.)

bp

77 °C/80 mmHg (lit.)

density

1.228 g/mL at 25 °C (lit.)

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Other Notes

根据要求提供批量采购价

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

77.0 °F - closed cup

flash_point_c

25 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Christopher G Nasveschuk et al.
The Journal of organic chemistry, 73(2), 612-617 (2007-12-20)
A modular and diastereoselective approach to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans is reported. The use of dioxepins containing an embedded vinyl acetal functionality leads to a Lewis acid-mediated [1,3] ring contraction to afford tetrahydrofurans in good yield and excellent diastereoselectivity. The
Jean-Louis Brochu et al.
Journal of combinatorial chemistry, 10(3), 405-420 (2008-04-19)
A modular, reagent-based approach to obtain different indoline alkaloid-inspired, tetracyclic architectures is developed. With the use of TBSOTf as a Lewis acid, we report here a tandem Michael-based approach that led to the synthesis of a diastereomeric mixture of tetracyclic
Hiromichi Fujioka et al.
Chemical communications (Cambridge, England), (29)(29), 4429-4431 (2009-07-15)
The remarkable effect of 2,2'-bipyridyl led to the successful development of the mild and highly chemoselective deprotection method of methoxymethyl (MOM) ethers using the combination of TMSOTf (or TESOTf) and 2,2'-bipyridyl; this method can be applied to the direct conversion
Sajal Kumar Maity et al.
Carbohydrate research, 354, 40-48 (2012-05-01)
N-(p-Methylphenylthio)-ε-caprolactam (1) in combination with trimethylsilyl trifluoromethanesulfonate (TMSOTf) provides an efficient thiophilic promoter system, capable of activating different thioglycosides. Both 'armed' and 'disarmed' thioglycosyl donors were activated for glycosidic bond formation. Notably, this reagent combination works well in reactivity-based one-pot
Stevenson Flemer et al.
Journal of peptide science : an official publication of the European Peptide Society, 18(1), 30-36 (2011-10-29)
A methodology is presented for the facile synthesis of Arg-containing peptides modified at the guanidine headgroup as substituted amidine cores. This process allows for the iterative construction of these Arg isosteres while the peptide is being built out on the

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