293474
4-溴-2-氟苯甲醚
97%
别名:
4-溴-2-氟-1-甲氧基苯
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关于此项目
线性分子式:
BrC6H3(F)OCH3
化学文摘社编号:
分子量:
205.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
219-096-2
MDL number:
Assay:
97%
InChI key
DWNXGZBXFDNKOR-UHFFFAOYSA-N
InChI
1S/C7H6BrFO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,1H3
SMILES string
COc1ccc(Br)cc1F
assay
97%
refractive index
n20/D 1.545 (lit.)
bp
84 °C/7 mmHg (lit.)
density
1.59 g/mL at 25 °C (lit.)
functional group
bromo, fluoro
General description
The IR and FT-IR spectra of 4-bromo-2-fluoroanisole have been investigated.
Application
4-Bromo-2-fluoroanisole has been used in the synthesis of:
- 1,4-bis[(3′-fluoro-4′-n alkoxyphenyl)ethynyl]benzenes with n=1-12
- 7-fluoro-6-methoxy-1-methyl-2-naphthaldehyde
- 5,7-difluoro-6-methoxy-1-methyl-2-naphthaldehyde
- liquid crystals with terminal difluoromethoxy group and backbone of phenylbicyclohexane
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Design of molecular architectures for polymeric mesophase formation.
Pugh C, et al.
Macromolecular Symposia, 98(1) (1995)
Vibrational spectra, first hyperpolarizability, HOMO-LUMO analysis of 4-bromo 2-fluro anisole.
Arivazhagan M, et al.
Indian Journal of Pure and Applied Physics, 50(5), 299-307 (2012)
Rolf W Hartmann et al.
Journal of enzyme inhibition and medicinal chemistry, 19(2), 145-155 (2004-09-29)
Regioselectively fluorinated 1-(naphth-2-ylmethyl)imidazoles 1a-h have been synthesized starting from the corresponding (naphth-2-yl)methanols (2). 2a-d have been obtained by LiAlH4-promoted reduction of fluorinated 1-methyl-2-naphthaldehydes. The latter were easily prepared in fairly good overall yields by ceric ammonium nitrate (CAN)-promoted oxidative addition
Syntheses of Phenylbicyclohexane Liquid Crystals with Terminal Difluoromethoxy Group [J].
Li J, et al.
Fine Chemicals / ????, 12, 004-004 (2004)
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