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经验公式(希尔记法):
C12H16O6
化学文摘社编号:
分子量:
256.25
UNSPSC Code:
12352201
NACRES:
NA.22
PubChem Substance ID:
EC Number:
215-978-6
Beilstein/REAXYS Number:
87517
MDL number:
产品名称
苯基-β-D-吡喃葡萄糖苷, ≥95.0%
InChI key
NEZJDVYDSZTRFS-RMPHRYRLSA-N
InChI
1S/C12H16O6/c13-6-8-9(14)10(15)11(16)12(18-8)17-7-4-2-1-3-5-7/h1-5,8-16H,6H2/t8-,9-,10+,11-,12-/m1/s1
SMILES string
OC[C@H]1O[C@@H](Oc2ccccc2)[C@H](O)[C@@H](O)[C@@H]1O
assay
≥95.0%
form
powder
optical activity
[α]25/D −70°, c = 1 in H2O
mp
176-178 °C (lit.)
Quality Level
Application
苯基 β- D -吡喃葡萄糖苷可用于:
- 作为合成 β - D -吡喃葡萄糖苷的各种衍生物的起始原料,具有潜在的抗 HIV 药物应用前景。
- 作为气相中糖苷的光谱分析模型。
- 作为 GC 和 GC-MS 定量分析中的内标。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
涉药品监管产品
此项目有
Synthesis of peptidomimetics based on iminosugar and ?-d-glucopyranoside scaffolds and inhibiton of HIV-protease.
Chery F, et al.
Tetrahedron, 60(31), 6597-6608 (2004)
Anke Reinders et al.
Plant, cell & environment, 29(10), 1871-1880 (2006-08-26)
Plant sucrose transporters (SUTs) are members of the glycoside-pentoside-hexuronide (GPH) cation symporter family (TC2.A.2) that is part of the major facilitator superfamily (MFS). All plant SUTs characterized to date function as proton-coupled symporters and catalyze the cellular uptake of sucrose.
4-(Arylamino)phenyl alpha-D-glucopyranosides as potential anti-HIV agents.
J C Briggs et al.
Carbohydrate research, 282(2), 293-298 (1996-03-18)
Sugars in the gas phase: the spectroscopy and structure of jet-cooled phenyl ?-D-glucopyranoside.
Talbot FO and Simons JP
Physical Chemistry Chemical Physics, 4(15), 3562-3565 (2002)
Ying Na et al.
Bioorganic chemistry, 39(3), 111-113 (2011-03-26)
The spontaneous hydrolysis of glycosylamines, where the aglycone is either a primary amine or ammonia, is over a hundred million-times faster than that of O- or S-glycosides. The reason for this (as pointed out by Capon and Connett in 1965)
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