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Merck
CN

290890

Sigma-Aldrich

二醋酸二丁基锡

technical grade

别名:

二正丁基二乙酸锡

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About This Item

线性分子式:
(CH3CH2CH2CH2)2Sn(OCOCH3)2
CAS号:
分子量:
351.03
Beilstein:
4136035
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

蒸汽密度

12 (vs air)

蒸汽压

1.3 mmHg ( 25 °C)

折射率

n20/D 1.471 (lit.)

bp

142-145 °C/10 mmHg (lit.)

mp

7-10 °C (lit.)

密度

1.32 g/mL at 25 °C (lit.)

SMILES字符串

CCCC[Sn](CCCC)(OC(C)=O)OC(C)=O

InChI

1S/2C4H9.2C2H4O2.Sn/c2*1-3-4-2;2*1-2(3)4;/h2*1,3-4H2,2H3;2*1H3,(H,3,4);/q;;;;+2/p-2

InChI key

JJLKTTCRRLHVGL-UHFFFAOYSA-L

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一般描述

二乙酸二丁基锡是一种有机锡化合物,常用作有机合成中的催化剂

应用

二乙酸二丁基锡可用作合成以下物质的催化剂:
  • 在三甲基甲硅基叠氮化物存在的情况下与各种腈反应制备Wittenberger四唑衍生物
  • 在二氯甲烷溶剂存在的情况下以各种异氰酸酯和醇反应制备氨基甲酸酯衍生物
  • 在4-甲基吗啉存在的情况下以芳基异氰酸酯和各种胺制备脲衍生物

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 - STOT SE 1 Oral

靶器官

thymus gland, thymus gland,Immune system

WGK

WGK 3

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Adrian Blaser et al.
Journal of medicinal chemistry, 55(1), 312-326 (2011-12-14)
Analogues of clinical tuberculosis drug (6S)-2-nitro-6-{[4-(trifluoromethoxy)benzyl]oxy}-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine (PA-824), in which the OCH(2) linkage was replaced with amide, carbamate, and urea functionality, were investigated as an alternative approach to address oxidative metabolism, reduce lipophilicity, and improve aqueous solubility. Several soluble monoaryl examples
TMSN3-Bu2Sn (OAc) 2: A modified and mild reagent system for Wittenberger tetrazole-synthesis
Yoneyama H, et al.
Tetrahedron Letters, 61, 151517-151517 (2020)
Yun-Chae Jung et al.
Scientific reports, 7(1), 17482-17482 (2017-12-14)
Amorphous poly(ethylene ether carbonate) (PEEC), which is a copolymer of ethylene oxide and ethylene carbonate, was synthesized by ring-opening polymerization of ethylene carbonate. This route overcame the common issue of low conductivity of poly(ethylene oxide)(PEO)-based solid polymer electrolytes at low
T Noda et al.
Toxicology, 167(3), 181-189 (2001-10-02)
The present study was designed to assess changes in the teratogenic potency of di-n-butyltin diacetate (DBTA) with increasing maternal age in rats. Pregnant Wistar rats of 3, 7.5 or 12 months were treated orally with DBTA at 0, 7.5, 10
Critical gestational day of teratogenesis by di-n-butyltin diacetate in rats.
T Noda et al.
Bulletin of environmental contamination and toxicology, 49(5), 715-722 (1992-11-01)

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