290785
Luperox® LP, 过氧化月桂酰
≥98%
别名:
过氧化月桂酰, 二（十二烷基）过氧化物, 过氧化二脱氧甘醇, 过氧化十二烷酰, 过氧化双月桂酰
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关于此项目
线性分子式:
[CH3(CH2)10CO]2O2
化学文摘社编号:
分子量:
398.62
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
203-326-3
Beilstein/REAXYS Number:
1804936
MDL number:
产品名称
Luperox® LP, 过氧化月桂酰, ≥98%
InChI key
YIVJZNGAASQVEM-UHFFFAOYSA-N
InChI
1S/C24H46O4/c1-3-5-7-9-11-13-15-17-19-21-23(25)27-28-24(26)22-20-18-16-14-12-10-8-6-4-2/h3-22H2,1-2H3
SMILES string
CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC
vapor density
13.7 (vs air)
assay
≥98%
form
solid
reaction suitability
reagent type: oxidant
mp
53-57 °C (lit.)
storage temp.
2-8°C
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Application
过氧化月桂酰可用作：
- 聚丙烯中的长链分支(LCB)引入剂，以改善其机械回收工艺。
- 一种温和的氧化剂和高效的氢抽取剂，可用于通过二聚化相应的二硫代氨基甲酸盐来制备二硫化合物。
- 制备离子印迹聚合物(IIP）中的引发剂。
- 一种引发剂和氧化剂，以在nBu3SnH存在的情况下通过氧化自由基环化反应构建刺桐环系。
Legal Information
Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.
signalword
Danger
hcodes
Hazard Classifications
Org. Perox. D
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Lauroyl peroxide.
IARC monographs on the evaluation of carcinogenic risks to humans, 71 Pt 3, 1485-1487 (1999-09-07)
Amparo Cantó-Mirapeix et al.
Electrophoresis, 29(21), 4399-4406 (2008-10-24)
The preparation of lauryl methacrylate (LMA)-based monolithic columns for CEC using lauroyl peroxide (LPO) as thermal initiator of polymerization has been investigated. The influence of initiator amount and composition of porogenic solvent on the physical and electrochromatographic properties of the
A J Klein-Szanto et al.
The Journal of investigative dermatology, 79(1), 30-34 (1982-07-01)
Free radical generating peroxides are potent skin irritants. After a single topical application of either 10, 20, or 40 mg of lauroyl peroxides or benzoyl peroxide on the dorsal skin of Sencar mice, the epidermal thickness increased markedly. No major
Y Sorata et al.
Biochimica et biophysica acta, 799(3), 313-317 (1984-06-29)
Photosensitized hemolysis of human erythrocytes by hematoporphyrin was suppressed by flavonols such as quercetin and rutin at submillimolar concentrations. The suppression of photohemolysis was accompanied by inhibition of lipid peroxidation by the reagents. Quercetin and rutin were photooxidized in the
Saeed Kakaei et al.
Organic & biomolecular chemistry, 11(33), 5481-5490 (2013-07-17)
A series of (2-alkylthiothiazolin-5-yl)methyl dodecanoates was synthesized from various alkyl N-allylcarbamodithioates and dilauroyl peroxide via a tandem radical hydrogen-abstraction-cyclization-substitution/combination reaction with a 5-exo-trig radical cyclization as a key step. The current route is the first, convenient, and efficient synthesis of
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