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质量水平
方案
98%
表单
powder
沸点
305 °C (lit.)
mp
109-112 °C (lit.)
SMILES字符串
c1cc(ccn1)-c2ccncc2
InChI
1S/C10H8N2/c1-5-11-6-2-9(1)10-3-7-12-8-4-10/h1-8H
InChI key
MWVTWFVJZLCBMC-UHFFFAOYSA-N
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一般描述
4,4′-bpy通常用于桥接金属中心以形成具有新特性的配位聚合物。4,4′-bpy配体可通过稳定磁序来介导顺磁性金属离子之间的电子效应。
4,4′-联吡啶(BPY)是一种主要用于制备配位聚合物的有机交联剂。它是一种吡啶衍生物,其中的吡啶基可以沿着碳碳结构旋转。它可以作为光电化学还原的催化剂。
应用
4,4′-联吡啶(4,4′-联吡啶,4,4′-bpy)和Co(NCS)2 溶液相互扩散形成单晶Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O和Co(NCS)2(4,4′-bipy)2·2(CH3CH2)2O。
BPY是一种配体,在过渡金属之间形成网络,从而形成配位键。可通过配位聚合物和BPY作为复合连接剂制备杂化纳米片。它由两个活性位点组成,可用于药物开发。
警示用语:
Danger
危险声明
预防措施声明
危险分类
Acute Tox. 3 Oral
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
从最新的版本中选择一种:
分析证书(COA)
Ultrafast photoinduced interfacial proton coupled electron transfer from cdse quantum dots to 4, 4′-bipyridine.
Journal of the American Chemical Society, 138(3), 884-892 (2016)
Crystal engineering of coordination polymers using 4, 4′-bipyridine as a bond between transition metal atoms.
Chemical Communications (Cambridge, England), 138(40), 4169-4179 (2006)
Chemical communications (Cambridge, England), (40)(40), 4169-4179 (2006-10-13)
Coordination polymers have attracted an enormous interest among chemists due to their novel physical and chemical properties. This review describes the role of 4,4'-bipyridine in discovering various coordination polymers with novel topologies that range from one-dimensional to three dimensional. The
Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4`-Bipyridine:? Syntheses and Structures
Inorganic Chemistry, 36 (5), 923- 929 null
Bottom-up approach for the preparation of hybrid nanosheets based on coordination polymers made of metal-diethyloxaloacetate complexes linked by 4, 4′-bipyridine.
CrystEngComm, 19(34), 4972-4982 (2017)
商品
Graphene is the building block for carbon nanomaterials with different dimensionalities.
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