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Merck
CN

289345

Sigma-Aldrich

氟化铯

99.9% trace metals basis

别名:

NSC 84270

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About This Item

经验公式(希尔记法):
CsF
CAS号:
分子量:
151.90
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22
方案:
99.9% trace metals basis

质量水平

方案

99.9% trace metals basis

mp

682 °C (lit.)

密度

4.115 g/mL at 25 °C (lit.)

SMILES字符串

[F-].[Cs+]

InChI

1S/Cs.FH/h;1H/q+1;/p-1

InChI key

XJHCXCQVJFPJIK-UHFFFAOYSA-M

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应用

可作为反应物用于:
  • 制备合成氟烯丙基化合物过程中的合成砌块
  • 在中性pH下和缓冲的有机-水混合溶液中,通过水解烷基甲硅烷基醚来合成醇
  • 炔基碘鎓盐的亲核氟化,以形成氟代乙烯基化合物
  • 亲核芳香取代(SNAr)反应
用于成功合成单晶Dion-Jacobson相CsLaTa2O7,其在光催化和超导性方面具有应用。
用作 Suzuki 交叉偶联反应合成邻取代联芳基化合物的碱。还用作质子介质(例如叔丁基和叔戊基醇)中主要卤化物和磺酸盐亲核氟化反应的试剂。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2

靶器官

Kidney,Adrenal gland

补充剂危害

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

从最新的版本中选择一种:

分析证书(COA)

Lot/Batch Number

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Journal of Organometallic Chemistry, 691, 5688-5688 (2006)
Dong Wook Kim et al.
Journal of the American Chemical Society, 128(50), 16394-16397 (2006-12-15)
Aprotic solvents are usually preferred for the SN2 reactions, because nucleophilicity and hence SN2 reactivity are severely retarded by the influence of the partial positive charge of protic solvents. In this work, we introduce a remarkable effect of using tertiary
L Bertollini et al.
Neuroreport, 5(5), 553-556 (1994-01-31)
The effect of intracellular fluoride ions on voltage-dependent calcium currents was tested during whole-cell voltage-clamp recordings in thalamic neurones acutely dissociated from young adult rats. It is demonstrated that 5-30 mM intracellular fluoride selectively and reversibly suppresses the high voltage-activated
J Kypr et al.
International journal of biological macromolecules, 13(1), 9-13 (1991-02-01)
Ten DNA fragments containing self-complementary alternating sequences of adenine and thymine differing in length and the starting nucleotide were studied by c.d. spectroscopy. It was found that d(TATATATA) but not d(ATATATAT), d(TATATA), d(CTATATAG) or (dT-dA)20 isomerized into the unusual X-DNA
E J Devor et al.
Alcohol and alcoholism (Oxford, Oxfordshire). Supplement, 1, 157-160 (1991-01-01)
The stimulated activity of platelet adenylate cyclase (AC) has been shown to be significantly lower among alcoholics compared with controls. In this report we demonstrate that stimulated platelet AC activity is under the control of a single major gene locus.

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