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质量水平
方案
99%
表单
liquid
折射率
n20/D 1.424 (lit.)
沸点
139 °C/739 mmHg (lit.)
密度
0.84 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)[Si](C)(C)O
InChI
1S/C6H16OSi/c1-6(2,3)8(4,5)7/h7H,1-5H3
InChI key
FGWRMMTYIZKYMA-UHFFFAOYSA-N
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应用
叔丁基二甲基硅烷醇可作为硅烷化试剂，通过硅烷化作用保护羟基基团。可用于：
- 通过催化不对称烯丙基取代反应制备α手性醚衍生物。
- 作为1,2-苯二甲醛聚合化的引发剂。
- 硅烯醇醚合成。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
113.0 °F - closed cup
闪点(°C)
45 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of hydrolytically stable porphyrin C-and S-glycoconjugates in high yields
Pasetto P, et al.
Chemical Communications (Cambridge, England), 81-82 (2001)
Reproducible and scalable synthesis of end-cap-functionalized depolymerizable poly (phthalaldehydes)
DiLauro AM, et al.
Macromolecules, 46(8), 2963-2968 (2013)
Enol Silyl Ethers via Copper (II)-Catalyzed C-O Bond Formation
Chan DG, et al.
Organic Letters, 13(10), 2778-2781 (2011)
Direct, Iridium-Catalyzed Enantioselective and Regioselective Allylic Etherification with Aliphatic Alcohols
Ueno S and Hartwig J
Angewandte Chemie (International ed. in English), 47(10), 1928-1931 (2008)
Corinne Nguyen et al.
Journal of medicinal chemistry, 49(14), 4183-4195 (2006-07-11)
We report the discovery of novel uracil-based acyclic compounds as inhibitors of deoxyuridine 5'-triphosphate nucleotidohydrolase (dUTPase), an enzyme involved in nucleotide metabolism that has been identified as a promising target for the development of antimalarial drugs. Compounds were assayed against
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