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288144

Sigma-Aldrich

三羰基二氯代钌二聚物

别名:

CORM-2

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About This Item

线性分子式:
[Ru(CO)3Cl2]2
CAS号:
22594-69-0
分子量:
512.01
MDL编号:
MFCD00011528
UNSPSC代码:
12161600
PubChem化学物质编号:
24857320
NACRES:
NA.22

质量水平

100

反应适用性

core: ruthenium
reagent type: catalyst

SMILES字符串

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Cl[Ru]Cl.Cl[Ru]Cl

InChI

1S/6CO.4ClH.2Ru/c6*1-2;;;;;;/h;;;;;;4*1H;;/q;;;;;;;;;;2*+2/p-4

InChI key

JYHHJVKGDCZCCL-UHFFFAOYSA-J

相关类别

应用

三羰基二氯钌(II)二聚体可用于氘化反应以标记仲胺。还可与环戊二烯并[l]菲基和c环戊二烯[a]苊基配体反应合成外消旋催化剂。
用于药理学研究的一氧化碳释放分子包括：
  • 凝血增强和纤溶脆弱性减弱
  • P2X4作为可能靶点的研究
  • 血栓生长或崩解的可能改变
  • 增强纤维蛋白原作为凝血酶底物的作用
  • 气体传输器对离子传输的调节

用作活性氧介导的细菌杀灭的一氧化碳供体

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR0080
MKCN3020
MKCG1927
MKCD8365
MKCB0224V

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What solvents can be used to dissolve Product 288144, Tricarbonyldichlororuthenium(II) dimer?

    This product is slightly soluble in chloroform and dichloromethane. It is also soluble in methanol and tetrahydrofuran, but it forms a solvent adduct.

  5. What are the potential applications for Product 288144, Tricarbonyldichlororuthenium(II) dimer?

    This product has been reported and used as a carbon monoxide releasing agent in biological systems, and a ruthenium catalyst.

  6. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  7. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

One-step exchange-labelling of piperidines, piperazines and dialkylamines with deuterium oxide: catalysis by various ruthenium complexes.
Alexakis E, et al.
Tetrahedron Letters, 46(25), 4291-4293 (2005)
Vance G Nielsen et al.
International journal of molecular sciences, 21(6) (2020-03-22)
Using thrombelastography to gain mechanistic insights, recent investigations have identified enzymes and compounds in Naja and Crotalus species' neurotoxic venoms that are anticoagulant in nature. The neurotoxic venoms of the four extant species of Dendroaspis (the Black and green mambas)
Cyclopenta [l] phenanthrenyl and Cyclopenta [a] acenaphthylenyl Half-Sandwich Complexes of Ruthenium as Racemization Catalysts for Secondary Alcohols.
Mavrynsky D, et al.
Organometallics, 28(2), 598-605 (2008)
Michał Majewski et al.
Antioxidants (Basel, Switzerland), 9(2) (2020-02-08)
Alcoholic leaf and petal fractions of Taraxacum officinale (dandelion) were previously demonstrated to exert in vitro antioxidant and antithrombotic activities in blood plasma and platelets. Eight-week-old male Wistar rats (n = 6) were supplemented for four weeks with dandelion fractions
Po-Min Yang et al.
Vascular pharmacology, 87, 209-218 (2016-10-11)
The production of nitric oxide (NO) by endothelial NO synthase (eNOS) plays a major role in maintaining vascular homeostasis. This study elucidated the potential role of carbon monoxide (CO)-releasing molecules (CORMs) in NO production and explored the underlying mechanisms in
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