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Merck
CN

287822

Sigma-Aldrich

三(邻甲基苯基)膦

97%

别名:

P(o-tol)3, 三(2-甲苯基)膦

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About This Item

线性分子式:
(CH3C6H4)3P
CAS号:
分子量:
304.37
Beilstein:
661212
EC 号:
MDL编号:
UNSPSC代码:
12352128
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

反应适用性

reaction type: Cross Couplings
reaction type: Silylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reagent type: ligand
reaction type: Heck Reaction

reagent type: ligand
reaction type: Negishi Coupling

reagent type: ligand
reaction type: Stille Coupling

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

123-125 °C (lit.)

官能团

phosphine

SMILES字符串

Cc1ccccc1P(c2ccccc2C)c3ccccc3C

InChI

1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3

InChI key

COIOYMYWGDAQPM-UHFFFAOYSA-N

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一般描述

三(对甲苯基)膦是一种配体,用于丙烷基碳酸酯的heck反应和suzuki 偶联。

应用

用于钌催化下醇直接胺化的配体。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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Valerio Cinà et al.
ChemPlusChem, 85(3), 391-398 (2020-03-03)
Hybrid nanostructures with switchable and reversible "blue-red-green" emission were efficiently synthesized. These nanostructures comprise polyhedral oligomeric silsesquioxanes (POSS) that behave as a nanocage that can be functionalized with terpyridine-based organic ligands, which can be easily complexed with europium (III) ions.
Majken Borup Thomsen et al.
Molecular imaging and biology, 22(5), 1290-1300 (2020-06-10)
Loss of neuronal synapse function is associated with a number of brain disorders. The [11C]UCB-J positron emission tomography (PET) tracer allows for in vivo examination of synaptic density, as it binds to synaptic vesicle glycoprotein 2A (SV2A) expressed in presynaptic
Chengjun Pan et al.
Macromolecular rapid communications, 40(12), e1900082-e1900082 (2019-04-04)
The molecular structure of polymers has a great influence on their thermoelectric properties; however, the relationship between the molecular structure of a polymer and its thermoelectric properties remains unclear. In this work, two benzo[1,2-b:4,5-b']dithiophene (BDT)-based conjugated polymers are designed and
Tetrahedron Letters, 47, 8881-8881 (2006)
Tri (o-tolyl) phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids
Junzhe X et al.
Chemical Communications (Cambridge, England), 54, 10451-10454 (2018)

相关内容

Catalexis平台通过数字化优化催化剂选择,识别出最有效的膦配体用于交叉偶联反应,从而增强了催化作用。

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

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