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Merck
CN

287784

Sigma-Aldrich

(1R,2R,3S,5R)-(-)-蒎烷二醇

99%

别名:

(-)-2-羟基异松蒎醇, [1R-(1α,2α,3α,5α)]-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇

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About This Item

经验公式(希尔记法):
C10H18O2
CAS号:
分子量:
170.25
Beilstein:
2039144
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

99%

旋光性

[α]21/D −8.6°, c = 6.5 in toluene

光学纯度

ee: 97% (GLC)

沸点

101-102 °C/1 mmHg (lit.)

mp

57-59 °C (lit.)

官能团

hydroxyl

SMILES字符串

CC1(C)[C@H]2C[C@H](O)[C@](C)(O)[C@@H]1C2

InChI

1S/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8+,10-/m1/s1

InChI key

MOILFCKRQFQVFS-BDNRQGISSA-N

应用

用于制备手性双烯丙基化试剂。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Simple, stable, and versatile double-allylation reagents for the stereoselective preparation of skeletally diverse compounds.
Feng Peng et al.
Journal of the American Chemical Society, 129(11), 3070-3071 (2007-02-24)
Gerald I Richard et al.
Applied spectroscopy, 62(5), 476-480 (2008-05-24)
The spectroscopic properties of a chiral boronic acid based resorcinarene macrocycle employed for chiral analysis were investigated. Specifically, the emission and excitation characteristics of tetraarylboronate resorcinarene macrocycle (TBRM) and its quantum yield were evaluated. The chiral selector TBRM was investigated

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