283606
氯化钯(II) 溶液
5 wt. % in 10 wt. % HCl, liquid
别名:
Dichloropalladium, Palladium dichloride, Palladous chloride
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关于此项目
线性分子式:
PdCl2
化学文摘社编号:
分子量:
177.33
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯化钯(II) 溶液, 5 wt. % in 10 wt. % HCl
SMILES string
Cl[Pd]Cl
InChI
1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChI key
PIBWKRNGBLPSSY-UHFFFAOYSA-L
form
liquid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
concentration
5 wt. % in 10 wt. % HCl
density
1.06 g/mL at 25 °C
Quality Level
General description
氯化钯(II)是钯(II)的代表性盐，作为前体用于制备各种反应的钯催化剂，如 Heck 偶联、Suzuki 偶联、Sonagashira 偶联和 Buchwald-Hartwig 偶联。它也可用作氧化剂。
Application
用于合成含半导体金属的聚合物，其中聚吡咯骨架的构象能量最小并且几乎是平面结构。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
flash_point_f
Not applicable
flash_point_c
Not applicable
存储类别
12 - Non Combustible Liquids
Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Maria Elisabete Machado et al.
Journal of chromatography. A, 1274, 165-172 (2013-01-10)
The separation of the organic sulfur compounds (OSC) of petroleum or its heavy fractions is a critical step and is essential for the correct characterization of these compounds, especially due to similar physical and chemical properties of polycyclic aromatic sulfur
Chun Liu et al.
Organic & biomolecular chemistry, 9(4), 1054-1060 (2010-12-15)
A simple and efficient protocol has been developed for the PdCl(2)-catalyzed ligand-free and aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with arylboronic acids in good to excellent yields in aqueous ethanol. A systematic investigation on the effect
Feng-Quan Yuan et al.
Chemical communications (Cambridge, England), 47(18), 5289-5291 (2011-04-01)
We present a PdCl(2)-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and
[(RCN)2PdCl2]-catalyzed E/Z isomerization of alkenes: a non-hydride binuclear addition-elimination pathway.
Emily H P Tan et al.
Angewandte Chemie (International ed. in English), 50(41), 9602-9606 (2011-09-23)
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