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检测方案
95%
形式
solid
bp
270 °C (lit.)
mp
59-61 °C (lit.)
SMILES字符串
Cc1cccc2cccc(C)c12
InChI
1S/C12H12/c1-9-5-3-7-11-8-4-6-10(2)12(9)11/h3-8H,1-2H3
InChI key
XAABPYINPXYOLM-UHFFFAOYSA-N
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一般描述
Mechanism of NO(2)(+) nitration of 1,8-dimethylnaphthalene has beeen investigated. Photolysis of the 1,8-dimethylnaphthalene/tetranitromethane charge-transfer complex affords the triad of 1,8-dimethylnaphthalene radical cation, nitrogen dioxide and trinitromethanide ion.
应用
1,8-Dimethylnaphthalene has been used in the preparation of 1,4-endoperoxides via dyesensitized photo-oxygenation reaction.
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Tanaka et al.
The Journal of organic chemistry, 65(10), 2972-2978 (2000-05-18)
The nitration of methylnaphthalenes with NO(2)BF(4) and NOBF(4) was examined in order to shed light on the controversial aromatic nitration mechanism, electrophilic vs charge-transfer process. The NO(2)(+) nitration of 1,8-dimethylnaphthalene showed a drastic regioselectivity change depending on the reaction temperature
Photochemical Nitration by Tetranitromethane. XVI. The Regiochemistry of Adduct Formation in the Photochemical Reaction of 1, 8-Dimethylnaphthalene and Tetranitromethane; Thermal 1, 3-Dipolar Nitro Addition Reactions.
Calvert Jl, et al.
Australian Journal of Chemistry, 47(7), 1211-1222 (1994)
Formation of 1, 4-endoperoxides from the dye-sensitized photo-oxygenation of alkyl-naphthalenes.
Wasserman HH and Larsen DL.
Journal of the Chemical Society. Chemical Communications, 5, 253-254 (1972)
Nien-Hsin Kao et al.
Marine pollution bulletin, 97(1-2), 319-332 (2015-06-08)
Three fishing harbors were investigated to study the polycyclic aromatic hydrocarbons in the sediments and trace possible anthropogenic sources by identification of cyclic terpenoid biomarkers. Seventeen terpanes, 10 steranes and 10 bicyclic sesquiterpanes in the marine diesel and the three
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