282332
苯磺酰氟
99%
别名:
Phenylsulfonyl fluoride
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线性分子式:
C6H5SO2F
化学文摘社编号:
分子量:
160.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-707-2
MDL number:
产品名称
苯磺酰氟, 99%
InChI key
IDIPWEYIBKUDNY-UHFFFAOYSA-N
InChI
1S/C6H5FO2S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
SMILES string
FS(=O)(=O)c1ccccc1
assay
99%
reaction suitability
reaction type: click chemistry
refractive index
n20/D 1.492 (lit.)
bp
207-208 °C (lit.)
density
1.333 g/mL at 25 °C (lit.)
Quality Level
Application
Benzenesulfonyl fluoride has been used in the preparation of α-sulfonyl phosphonates by direct sulfonylation of lithiated alkyl phosphonates.
General description
The gas-phase fluorine migration reactions of radical cations of benzenesulfonyl fluoride have been studied by electron ionization tandem mass spectrometry.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
188.6 °F - closed cup
flash_point_c
87 °C - closed cup
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The gas-phase reactions of Aryl-SF5(·+) and Aryl-SO2F(·+) have been studied with the electron ionization tandem mass spectrometry. Such reactions involve F-atom migration from the S-atom to the aryl group affording the product ion Aryl-F(·+) by subsequent expulsion of SF4 or
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