等级
technical grade
质量水平
检测方案
90%
形式
liquid
折射率
n20/D 1.442 (lit.)
bp
130 °C (lit.)
mp
-41.5 °C (lit.)
密度
0.858 g/mL at 25 °C (lit.)
SMILES字符串
C\C(C)=C\C(C)=O
InChI
1S/C6H10O/c1-5(2)4-6(3)7/h4H,1-3H3
InChI key
SHOJXDKTYKFBRD-UHFFFAOYSA-N
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一般描述
氯化锌催化异亚丙基丙酮与乙酰乙酸乙酯的缩合反应已有报道 。
应用
异亚丙基丙酮的用途如下:
- 在 2,3,4,5-四氢-1,3,3-三甲基安乃近的合成中,定向合成二氢卟吩和二氢卟吩的关键构件
- 咪唑涂层毛细管电泳柱制备中的中性标记物
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 1
闪点(°F)
87.8 °F
闪点(°C)
31 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Organic process research & development, 9(5), 651-659 (2005-01-01)
2,3,4,5-Tetrahydro-1,3,3-trimethyldipyrrin (1) is a crucial building block in the rational synthesis of chlorins and oxochlorins. The prior 5-step synthesis of 1 from pyrrole-2-carboxaldehyde (2) employed relatively simple and well-known reactions yet suffered from several drawbacks, including limited scale (>/= 0.5
Condensation of mesityl oxide with acetoacetic ester.
The Journal of Organic Chemistry, 35(4), 1053-1056 (1970)
Journal of chromatography. A, 897(1-2), 383-392 (2000-12-29)
An imidazole-coated capillary column for electrophoresis has been prepared by means of organosilanization. With mesityl oxide as neutral marker, the results indicated that the electroosmotic flow of the bonded phase displays a dramatic difference in pH dependence in comparison with
The Journal of organic chemistry, 71(4), 1668-1676 (2006-02-14)
The mechanism of the formation of substituted quinolines from anilines and alpha,beta-unsaturated ketones has been studied by the use of 13C-labeled ketones in cross-over experiments. In the reaction of doubly labeled 13C(2,4) mesityl oxide, a 100% scrambling of the label
Journal of chromatography, 588(1-2), 315-320 (1991-12-27)
Expressions are formulated for the prediction of solute migration time and resolution as a function applied voltage and buffer concentration in capillary zone electrophoresis. The resolution equation assumes that solute diffusion is the only operative zone-broadening mechanism. A resolution surface
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