281697
(R)-(-)-2-吡咯烷甲醇
99%
别名:
(R)-(-)-2-(羟甲基)吡咯烷, D-脯氨醇
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关于此项目
经验公式（希尔记法）:
C5H11NO
化学文摘社编号:
分子量:
101.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1523669
产品名称
(R)-(-)-2-吡咯烷甲醇, 99%
InChI
1S/C5H11NO/c7-4-5-2-1-3-6-5/h5-7H,1-4H2/t5-/m1/s1
SMILES string
OC[C@H]1CCCN1
InChI key
HVVNJUAVDAZWCB-RXMQYKEDSA-N
assay
99%
optical activity
[α]20/D −31°, c = 1 in toluene
refractive index
n20/D 1.4849 (lit.)
bp
74-76 °C/2 mmHg (lit.)
density
1.025 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
Application
用于不对称合成的多功能试剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
186.8 °F - closed cup
flash_point_c
86 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Silvia Dei et al.
Bioorganic & medicinal chemistry, 11(14), 3153-3164 (2003-06-24)
Four out of the eight possible stereoisomers of 1-methyl-2-(2-methyl-1,3-dioxolan-4-yl)pyrrolidine, 1-methyl-2-(2-methyl-1,3-oxathiolan-5-yl)pyrrolidine and the corresponding iodomethylates have been synthesised. They were formally derived from hybridisation of potent though unselective agonists studied before, such as 1,3-dioxolane 1 and 1,3-oxathiolane 2, with the structure
Tetrahedron Asymmetry, 15, 519-523 (2004)
Emily M Christensen et al.
The Journal of biological chemistry, 295(52), 18316-18327 (2020-10-29)
Pyrroline-5-carboxylate reductase 1 (PYCR1) catalyzes the biosynthetic half-reaction of the proline cycle by reducing Δ1-pyrroline-5-carboxylate (P5C) to proline through the oxidation of NAD(P)H. Many cancers alter their proline metabolism by up-regulating the proline cycle and proline biosynthesis, and knockdowns of
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