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Merck
CN

281646

Sigma-Aldrich

2,3-双(2-吡啶基)吡嗪

98%

别名:

2,3-二-2-吡啶基吡嗪

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About This Item

经验公式(希尔记法):
C14H10N4
CAS号:
分子量:
234.26
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

mp

168-170 °C (lit.)

SMILES字符串

c1ccc(nc1)-c2nccnc2-c3ccccn3

InChI

1S/C14H10N4/c1-3-7-15-11(5-1)13-14(18-10-9-17-13)12-6-2-4-8-16-12/h1-10H

InChI key

WTZDTUCKEBDJIM-UHFFFAOYSA-N

应用

2,3-(2-吡啶基)吡嗪(dpp)已被用于:
  • 作为超分子分子的构成单元
  • 用于制备荧光配合物Ru(bpy)2(dpp)2+和 (bpy)2Ru-(dpp)Ru(bpp)24+ [bpy=2,2′-联吡啶]
  • 与V(IV)O和Cu(II)离子用于制备二元和三元系统

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Inorganic Chemistry, 32, 3003-3003 (1993)
Jing Xiang et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 741-750 (2018-12-19)
A series of polynuclear metal complexes, [Cu2(L1)(PPh3)4](ClO4)2 (1), [Cu3(L2)(PPh3)6](ClO4) (2), [Cu3(L3)(PPh3)6] (3), [Ag2(L1)(PPh3)4](BF4)2 (4), [Ag4(L2)2(PPh3)6] (5) and [Ag3(L3)(PPh3)5] (6), have been obtained from the reactions of the highly conjugated bridging ligands 2,3-bis(2-pyridyl)pyrazine (L1), 2,3-bis(2-tetrazoyl)pyrazine (H2L2) and 2,3-bis(2-tetrazoyl)imidazole (H3L3) with [Cu(MeCN)4]ClO4
Daniele Sanna et al.
Dalton transactions (Cambridge, England : 2003), 41(41), 12824-12838 (2012-09-15)
The binary and ternary systems formed by V(IV)O and Cu(II) ions with ligands (L) based on the pyridine ring (1,10-phenanthroline (phen), 2,2'-bipyridine (bpy), 2,2':6',2''-terpyridine (terpy), 2,2'-bipyrimidine (bpm) and 2,3-bis(2-pyridyl)pyrazine (bpp)) were studied, combining spectroscopic (EPR and UV-vis), pH-potentiometric and computational
Spectroscopic and electrochemical properties of the dimer tetrakis (2, 2'-bipyridine)(. mu.-2, 3-bis (2-pyridyl) pyrazine) diruthenium (II) and its monomeric analog.
Braunstein CH, et al.
Inorganic Chemistry, 23(7), 857-864 (1984)
Cléia Justino Nunes et al.
Journal of inorganic biochemistry, 149, 49-58 (2015-05-30)
In this work, the influence of two new dinuclear copper(II) complexes in the viability of melanoma cells (B16F10 and TM1MNG3) was investigated, with the aim of verifying possible correlations between their cytotoxicity and their structure. One of the complexes had

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