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About This Item
经验公式（希尔记法）:
C6H14N2O
CAS号:
分子量:
130.19
Beilstein:
1523794
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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方案
95%
表单
liquid
旋光性
[α]20/D −79°, neat
光学纯度
ee: 97% (GLC)
折射率
n20/D 1.465 (lit.)
沸点
42 °C/1.8 mmHg (lit.)
密度
0.97 g/mL at 25 °C (lit.)
官能团
ether
SMILES字符串
COC[C@@H]1CCCN1N
InChI
1S/C6H14N2O/c1-9-5-6-3-2-4-8(6)7/h6H,2-5,7H2,1H3/t6-/m0/s1
InChI key
BWSIKGOGLDNQBZ-LURJTMIESA-N
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应用
(S)-(-)-1-氨基-2-(甲氧甲基)吡咯烷可作为手性辅助剂，用于(S)-2-乙基己酸和(S)-2-n-丙基-4-戊烯酸的不对称合成。在溴化锌存在下，与(E)-链烯基-环己基磺酸盐发生1,4加成反应以形成β-肼基-环己基磺酸盐。
与羰基化合物发生缩合反应，生成水合腙，后者在高度对映选择性合成中是有用的合成物。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
161.6 °F - closed cup
闪点(°C)
72 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Tetrahedron, 49, 1821-1821 (1993)
Ludovica F Buttó et al.
Inflammatory bowel diseases, 25(1), 14-26 (2018-10-09)
TNF-like cytokine 1A (TL1A) and its functional receptor, death-domain-receptor-3 (DR3), are multifunctional mediators of effector and regulatory immunity. We aimed to evaluate the functional role and therapeutic potential of TL1A/DR3 signaling in Crohn's disease-like ileitis. Ileitis-prone SAMP1/YitFc (SAMP) and TNFΔARE/+
Asymmetric Synthesis of ?-Amino-cyclohexyl Sulfonates via azaMichael Addition
Enders D and Wallert S.
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Synthesis, 725-725 (1993)
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