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质量水平
等级
technical
方案
~70% (GC)
表单
liquid
杂质
~30% 3-chloro-1-butene
折射率
n20/D 1.430
沸点
85-86 °C (lit.)
溶解性
water: soluble 14 g/L at 20 °C
密度
0.923 g/mL at 20 °C (lit.)
官能团
alkyl halide
chloro
SMILES字符串
C\C=C\CCl
InChI
1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+
InChI key
YTKRILODNOEEPX-NSCUHMNNSA-N
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一般描述
Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.
应用
Crotyl chloride has been used:
- to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
- in the preparation of (E)-crotyltrichlorosilane
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
10.4 °F - closed cup
闪点(°C)
-12 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.
Wang W, et al.
Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)
The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.
Furuya N and Sukawa T.
Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)
Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.
Kira M, et al.
Tetrahedron Letters, 30(9), 1099-1102 (1989)
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