推荐产品
蒸汽压
6.05 psi ( 20 °C)
方案
98%
表单
liquid
折射率
n20/D 1.378 (lit.)
沸点
44-46 °C (lit.)
密度
0.668 g/mL at 25 °C (lit.)
SMILES字符串
CC[SiH](C)C
InChI
1S/C4H12Si/c1-4-5(2)3/h5H,4H2,1-3H3
InChI key
QGBMSFLTRRZTGI-UHFFFAOYSA-N
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应用
二甲基乙基硅烷可用作:
- 无配体碳硫键切断反应的还原剂。
- 钯催化的1,6-二烯的环异构化反应的促进剂。
警示用语:
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-29.2 °F - closed cup
闪点(°C)
-34 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Development, synthetic scope, and mechanistic studies of the palladium-catalyzed cycloisomerization of functionalized 1, 6-dienes in the presence of silane
Kisanga P and Widenhoefer RA
Journal of the American Chemical Society, 122(41), 10017-10026 (2000)
Nekane Barbero et al.
Organic letters, 14(3), 796-799 (2012-01-20)
A catalytic reductive cleavage of C(sp(2))- and C(sp(3))-SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches.
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