质量水平
检测方案
95%
SMILES字符串
[Na+].CCC(C)(C)[O-]
InChI
1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
InChI key
CGRKYEALWSRNJS-UHFFFAOYSA-N
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应用
钠 叔 -五氧化物 (NaO t -Am) 是醇类 和仲胺 N -氰化反应中常用的碱。也可用于制备络合还原剂,将 1-卤萘和取代卤苯还原为相应的的萘和苯。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
WGK
WGK 1
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Deoxycyanamidation of Alcohols with N-Cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS).
Organic Letters, 19(14), 3835-3838 (2017)
N-Cyanation of Secondary Amines Using Trichloroacetonitrile.
Organic Letters, 18(21), 5528-5531 (2016)
Activation of reducing agents: Sodium hydride-containing ?complex reducing agents?: I. Reduction of aromatic halides.
Journal of Organometallic Chemistry, 92(1), 43-47 (1975)
Chemistry (Weinheim an der Bergstrasse, Germany), 21(28), 10160-10169 (2015-06-11)
Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as their bifluoride salts. These reactions proceed most efficiently when the supporting ligands are expanded N-heterocyclic carbenes (NHCs)
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