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方案
97%
表单
solid
mp
72-74 °C (lit.)
溶解性
acetone: soluble 25 mg/mL, clear, colorless to yellow
官能团
phenyl
thioether
SMILES字符串
C1CSC(SC1)c2ccccc2
InChI
1S/C10H12S2/c1-2-5-9(6-3-1)10-11-7-4-8-12-10/h1-3,5-6,10H,4,7-8H2
InChI key
GXKPARDRBFURON-UHFFFAOYSA-N
一般描述
The full set of NMR spectral parameters (1H, 13C, 31P) for 2-phenyl-1,3-dithiane has been reported.
应用
2-Phenyl-1,3-dithiane is a versatile acyl anion equivalent and has been used in the preparation of benzaldehyde-1-d.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Synthesis of 1-deuterioaldehydes. Benzaldehyde-1-D.
The Journal of Organic Chemistry, 31(12), 4303-4304 (1966)
NMR spectral analysis of 1, 3, 2-dithiaphosphorinanes and 1, 3-dithianes.
Org. Magn. Reson., 7(2), 76-77 (1975)
Journal of the American Chemical Society, 119, 6925-6925 (1997)
Journal of the American Chemical Society, 125(47), 14435-14445 (2003-11-20)
The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of highly functionalized intermediates for complex molecule synthesis
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