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Merck
CN

279617

Sigma-Aldrich

2-苯基-1,3-二噻烷

97%

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About This Item

经验公式(希尔记法):
C10H12S2
CAS号:
分子量:
196.33
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

97%

表单

solid

mp

72-74 °C (lit.)

溶解性

acetone: soluble 25 mg/mL, clear, colorless to yellow

官能团

phenyl
thioether

SMILES字符串

C1CSC(SC1)c2ccccc2

InChI

1S/C10H12S2/c1-2-5-9(6-3-1)10-11-7-4-8-12-10/h1-3,5-6,10H,4,7-8H2

InChI key

GXKPARDRBFURON-UHFFFAOYSA-N

一般描述

The full set of NMR spectral parameters (1H, 13C, 31P) for 2-phenyl-1,3-dithiane has been reported.

应用

2-Phenyl-1,3-dithiane is a versatile acyl anion equivalent and has been used in the preparation of benzaldehyde-1-d.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

Synthesis of 1-deuterioaldehydes. Benzaldehyde-1-D.
Seebach D, et al.
The Journal of Organic Chemistry, 31(12), 4303-4304 (1966)
NMR spectral analysis of 1, 3, 2-dithiaphosphorinanes and 1, 3-dithianes.
Martin J and Robert JB.
Org. Magn. Reson., 7(2), 76-77 (1975)
Smith, A. B., III; Boldi, A. M.
Journal of the American Chemical Society, 119, 6925-6925 (1997)
Amos B Smith et al.
Journal of the American Chemical Society, 125(47), 14435-14445 (2003-11-20)
The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of highly functionalized intermediates for complex molecule synthesis

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