277460
3-(甲硫基)丙醛
96%
别名:
3-(甲基巯基)丙醛, 3-（甲硫基）丙醛, NSC 15874, 甲硫基丙醛
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关于此项目
线性分子式:
CH3SCH2CH2CHO
化学文摘社编号:
分子量:
104.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-882-5
Beilstein/REAXYS Number:
1739289
MDL number:
Assay:
96%
Form:
liquid
InChI key
CLUWOWRTHNNBBU-UHFFFAOYSA-N
InChI
1S/C4H8OS/c1-6-4-2-3-5/h3H,2,4H2,1H3
SMILES string
CSCCC=O
vapor density
>1 (vs air)
vapor pressure
760 mmHg ( 165 °C)
assay
96%
form
liquid
refractive index
n20/D 1.483 (lit.)
bp
165-166 °C (lit.)
density
1.043 g/mL at 25 °C (lit.)
functional group
aldehyde, thioether
storage temp.
2-8°C
Quality Level
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General description
3-（甲硫基）丙醛 (methional) 是食品中通过 Strecker 降解进行化学蛋氨酸转化的主要产物 。
Application
3-甲硫基丙醛用作以下反应试剂：
- 氧化偶联和化学选择性氧化
- 分子间炔烃的氢化酰化反应
- 硫化物氧化为亚砜
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
165.2 °F - closed cup
flash_point_c
74 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
M M W Etschmann et al.
Applied microbiology and biotechnology, 80(4), 579-587 (2008-07-04)
Yeasts can convert amino acids to flavor alcohols following the Ehrlich pathway, a reaction sequence comprising transamination, decarboxylation, and reduction. The alcohols can be further derivatized to the acetate esters by alcohol acetyl transferase. Using L: -methionine as sole nitrogen
Ethylene formation from methional.
W A Pryor et al.
Biochemical and biophysical research communications, 81(2), 498-503 (1978-03-30)
A Escudero et al.
Journal of agricultural and food chemistry, 48(9), 4268-4272 (2000-09-20)
A young white wine that had undergone spontaneous oxidation and showed a strong off-flavor reminiscent of cooked vegetables was demixed by salting out to obtain an ethanolic extract that retained the off-flavor of the wine, as was demonstrated by sensory
F Amárita et al.
FEMS microbiology letters, 204(1), 189-195 (2001-10-30)
Lactic acid bacteria were screened for methional production from 4-methylthio-2-ketobutanoate. Only Lactococcus lactis IFPL730 produced high amounts of methional. It was demonstrated that production of this compound was an exclusively enzymatic reaction. The present work describes for the first time
E Hiltbrand et al.
Current medicinal chemistry, 16(10), 1184-1191 (2009-04-10)
An intraperitoneal (IP) monotherapy in nu/nu mice with subcutaneous xenografts of a human prostate epithelial cancer cell line:DU145 was undertaken with an aldehyde dehydrogenase 3 inhibitor MATE, that is a potent apoptogen on (DU145) in culture but not on their
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