277371
1-三甲硅基吡咯烷
97%
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关于此项目
经验公式（希尔记法）:
C7H17NSi
化学文摘社编号:
分子量:
143.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
239-149-3
Beilstein/REAXYS Number:
1304636
MDL number:
产品名称
1-三甲硅基吡咯烷, 97%
InChI key
NQLVIKZJXFGUET-UHFFFAOYSA-N
InChI
1S/C7H17NSi/c1-9(2,3)8-6-4-5-7-8/h4-7H2,1-3H3
SMILES string
C[Si](C)(C)N1CCCC1
assay
97%
form
liquid
refractive index
n20/D 1.433 (lit.)
bp
139-140 °C (lit.)
density
0.821 g/mL at 25 °C (lit.)
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Application
1-(Trimethylsilyl)pyrrolidine (N-trimethylsilyl pyrrolidine) has been used in:
- ring opening reaction of L-serine β-lactone to yield corresponding 5-amino-L-alanine derivatives
- the preparation of iminium triflate salts
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
39.2 °F - closed cup
flash_point_c
4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Exocyclic iminium salts as catalysts for alkene epoxidation by Oxone?.
Armstrong A, et al.
Tetrahedron, 55(8), 2341-2352 (1999)
Reaction of trimethylsilylamines with N-Cbz-l-serine-?-lactone: A convenient route to optically pure ?-amino-l-alanine derivatives.
Ratemi ES and Vederas JC.
Tetrahedron Letters, 35(41), 7605-7608 (1994)
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