所有图片(1)
About This Item
线性分子式:
(CH3)2C=CHBr
CAS号:
分子量:
135.00
Beilstein:
1733844
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.462 (lit.)
沸点
92 °C (lit.)
密度
1.318 g/mL at 25 °C (lit.)
官能团
alkyl halide
bromo
储存温度
2-8°C
SMILES字符串
C\C(C)=C\Br
InChI
1S/C4H7Br/c1-4(2)3-5/h3H,1-2H3
InChI key
DEFNUDNHTUZJAL-UHFFFAOYSA-N
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应用
1-Bromo-2-methyl-1-propene has been used in:
- preparation of esters of 2,4-dienoic acids via palladium catalyzed reaction with methyl acrylate in the presence of triethylamine
- total synthesis of ocular age pigment, A2-E
- synthesis of 3-nor-geraniol [2H2]
其他说明
储存时颜色可变暗
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
44.6 °F - closed cup
闪点(°C)
7 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Palladium-catalyzed conjugated diene synthesis from vinylic halides and olefinic compounds.
Dieck HA and Heck RF.
The Journal of Organic Chemistry, 40(8), 1083-1090 (1975)
Biosynthesis of iridoid monoterpenes in insects: Defensive secretions from larvae of leaf beetles (coleoptera: chrysomelidae).
Veith M, et al.
Tetrahedron, 50(23), 6859-6874 (1994)
Total synthesis of the ocular age pigment A2-E: a convergent pathway.
Ren R X-F, et al.
Journal of the American Chemical Society, 119(15), 3619-3620 (1997)
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