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Merck
CN

277053

Sigma-Aldrich

(S)-(+)-2-(甲氧基甲基)吡咯烷

99%

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别名:
O-甲基-L-脯氨醇, SMP
经验公式(希尔记法):
C6H13NO
CAS号:
分子量:
115.17
Beilstein:
3587324
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

检测方案

99%

形式

liquid

旋光性

[α]20/D +2.4°, c = 2 in benzene

折射率

n20/D 1.4457 (lit.)

bp

62 °C/40 mmHg (lit.)

密度

0.933 g/mL at 25 °C (lit.)

SMILES字符串

COC[C@@H]1CCCN1

InChI

1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

InChI key

CHPRFKYDQRKRRK-LURJTMIESA-N

应用

手性助剂,用于不对称合成炔丙醇 和 4-硝基环己酮, 以及用于不对称 Michael 加成反应生成烯酮。
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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