所有图片(2)
About This Item
经验公式（希尔记法）:
C5H7Cl
CAS号:
分子量:
102.56
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
97%
折射率
n20/D 1.4651 (lit.)
沸点
113-115 °C (lit.)
密度
1.035 g/mL at 25 °C (lit.)
官能团
chloro
储存温度
2-8°C
SMILES字符串
ClC1=CCCC1
InChI
1S/C5H7Cl/c6-5-3-1-2-4-5/h3H,1-2,4H2
InChI key
UJUIJZWQFDQKHO-UHFFFAOYSA-N
一般描述
1-Chloro-1-cyclopentene undergoes cross-coupling reaction with arylboronic acids, arylzinc reagents and thiols catalyzed by air-stable palladium complexes to yield the corresponding styrene derivatives, biaryls, and thioethers. Palladium-catalyzed aminocarbonylations of 1-chloro-1-cyclopentene and benzyl amine has been studied.
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
48.2 °F - closed cup
闪点(°C)
9 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
George Y Li
The Journal of organic chemistry, 67(11), 3643-3650 (2002-05-25)
Air-stable palladium complexes [(t-Bu)(2)P(OH)](2)PdCl(2), [(t-Bu)(2)P(OH)PdCl(2)](2), and [[(t-Bu)(2)PO...H...OP((t-Bu)(2)]PdCl](2) serve as efficient catalysts for a variety of cross-coupling reactions of vinyl and aryl chlorides with arylboronic acids, arylzinc reagents, and thiols to yield the corresponding styrene derivatives, biaryls, and thioethers. (31)P NMR
Aminocarbonylations of alkenyl phosphates, chlorides, bromides, and triflates with Mo(CO)6 as a solid CO source.
Lagerlund O, et al.
Tetrahedron, 65(36), 7646-7652 (2009)
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