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27395

1,4-桉叶素

Name: 1,4-桉叶素
Brand: ALDRICH

technical, mixture of isomers, ≥85% (GC)

别名:

1-甲基-4-(1-甲乙基)-7-氧杂二环[2.2.1]庚烷

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₈O

化学文摘社编号:

470-67-7

分子量:

154.25

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57648243

EC Number:

207-428-9

Beilstein/REAXYS Number:

104974

MDL number:

MFCD00209502

Assay:

≥85% (GC)

Form:

liquid

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属性

Quality Level

100

grade

technical

assay

≥85% (GC)

form

liquid

composition

1,4-cineol, ~75% , 1,8-cineol, ~15%

refractive index

n20/D 1.445 (lit.), n20/D 1.447

bp

65 °C/16 mmHg (lit.)

mp

−46 °C (lit.)

density

0.887 g/mL at 25 °C (lit.)

functional group

ether

SMILES string

CC(C)C12CCC(C)(CC1)O2

InChI

1S/C10H18O/c1-8(2)10-6-4-9(3,11-10)5-7-10/h8H,4-7H2,1-3H3/t9-,10+

InChI key

RFFOTVCVTJUTAD-AOOOYVTPSA-N

说明

General description

1,4-Cineole is present in eucalyptus oil. It activated both human TRPA1 (a sensor of noxious cold) and human TRPM 8 (a thermosensitive receptor). It is a natural monoterpene that inhibits plant growth.

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pictograms

GHS02

signalword

Warning

hcodes

H226

pcodes

P210 - P233 - P240 - P241 - P242 - P243

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

116.6 °F - closed cup

flash_point_c

47 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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[GC-MS analysis of constituents of essential oils from stems of Ephedra sinica Stapf, E. intermedia Schrenk et C.A. Mey. and E. equisetina Bge].

L Ji et al.

Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 22(8), 489-492 (1997-08-01)

The essential oils from the dried stems of Ephedra sinica, E. intermedia and E. equisetina were analyzed by GC-MS qualitatively and GC quantitatively. One hundred and twenty-seven constituents were identified, l-alpha-terpineol (31.64%) in E. sinica, 1,4-cineole (12.80%) in E. intermedia

A soluble Bacillus cereus cytochrome P-450cin system catalyzes 1,4-cineole hydroxylations.

W Liu et al.

Applied and environmental microbiology, 59(11), 3889-3893 (1993-11-01)

A cytochrome P-450-dependent monooxygenase system that catalyzes the stereospecific hydroxylation of the monoterpene substrate 1,4-cineole was demonstrated in cell-free preparations of Bacillus cereus UI-1477. 1,4-Cineole hydroxylations were catalyzed by a 100,000 x g (1-h)-centrifuging soluble, hexane-inducible enzyme that activated and

Roles of cytochrome P450 3A enzymes in the 2-hydroxylation of 1,4-cineole, a monoterpene cyclic ether, by rat and human liver microsomes.

M Miyazawa et al.

Xenobiotica; the fate of foreign compounds in biological systems, 31(10), 713-723 (2001-11-07)

1. Oxidation of 1,4-cineole, a monoterpene cyclic ether, was studied in rat and human liver microsomes and recombinant cytochrome P450 (P450 or CYP) enzymes expressed in insect cells in which human P450 and NADPH-P450 reductase cDNAs have been introduced. On

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全球贸易项目编号

货号	GTIN
633046-5G	04061832721484
633046-25G	04061833046074
27395-50ML-F	04061826151822