质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.4298 (lit.)
bp
98-101 °C (lit.)
密度
0.938 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
O=CC1CC1
InChI
1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2
InChI key
JMYVMOUINOAAPA-UHFFFAOYSA-N
应用
环丙甲醛通过与[Ni(cod)(2)]（cod = 1,5-环辛二烯）和PBu(3)反应，可合成eta(2)-烯酮镍配合物。
用于制备环亚丙基四氢萘酮，其通过对映选择性钯催化的[3+2]TMM环加成反应，得到手性螺环稠合环戊烯。
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
M Cowart et al.
Bioorganic & medicinal chemistry letters, 11(1), 83-86 (2001-01-05)
The synthesis and SAR of a novel series of non-nucleoside pyridopyrimidine inhibitors of the enzyme adenosine kinase (AK) are described. It was found that pyridopyrimidines with a broad range of medium and large non-polar substituents at the 5-position potently inhibited
Wang, Z. et al
Tetrahedron Letters, 41, 4007-4007 (2000)
Takashi Tamaki et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(39), 10083-10091 (2009-09-01)
Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta(2)-enonenickel complexes (2 a-c). In the presence of PCy(3) (Cy =
Barry M Trost et al.
Journal of the American Chemical Society, 128(41), 13328-13329 (2006-10-13)
Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diastereoselective process. We report a palladium-catalyzed asymmetric [3 + 2] trimethylenemethane (TMM) cycloaddition between 3-acetoxy-2-trimethylsilylmethyl-1-propene
Krzysztof Z Łączkowski et al.
Medicinal chemistry research : an international journal for rapid communications on design and mechanisms of action of biologically active agents, 27(9), 2125-2140 (2018-09-18)
Synthesis and investigation of antifungal, anticonvulsant and anti-Toxoplasma gondii activities of ten novel (2-(cyclopropylmethylidene)hydrazinyl)thiazole 3a-3j are presented. Among the derivatives, compounds 3a-3d and 3f-3j possess very high activity against Candida spp. ATCC with MIC = 0.015-7.81 µg/ml. Compounds 3a-3d and 3f-3j possess also
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