所有图片(3)
About This Item
线性分子式:
(CH3)3COCOC≡CCOOC(CH3)3
CAS号:
分子量:
226.27
Beilstein:
1957547
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
98%
表单
solid
沸点
80-82 °C/0.05 mmHg (lit.)
mp
33-37 °C (lit.)
官能团
ester
SMILES字符串
CC(C)(C)OC(=O)C#CC(=O)OC(C)(C)C
InChI
1S/C12H18O4/c1-11(2,3)15-9(13)7-8-10(14)16-12(4,5)6/h1-6H3
InChI key
FBCRUXRGQFLOMC-UHFFFAOYSA-N
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一般描述
以阳离子铑（I）/(R)-tol-binap配合物为催化剂对乙炔二羧酸二叔丁酯、甲硅烷基乙炔和丙烯酰胺的交叉环三聚进行了研究。糖基叠氮化物可与乙二炔二羧酸二叔丁酯进行1,3-偶极环加成反应。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jun Hara et al.
Angewandte Chemie (International ed. in English), 53(11), 2956-2959 (2014-02-08)
It has been established that a cationic rhodium(I)/(R)-tol-binap complex catalyzes the cross-cyclotrimerization of silylacetylenes, di-tert-butyl acetylenedicarboxylates, and acrylamides with excellent chemo-, regio-, and enantioselectivities. Unsymmetrical alkynoates can also be employed in place of di-tert-butyl acetylenedicarboxylate for this process, but with
W Bröder et al.
Carbohydrate research, 249(1), 221-241 (1993-10-18)
Glycosyl azides provide reliable anomeric protection stable to conditions for hydrolytic removal of ester groups, for reductive opening or release of acetalic diol protection, for the introduction of ether-type protection, and for glycosylation processes. The utility of this anomeric protection
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