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方案
98%
表单
liquid
包含
potassium carbonate as stabilizer
折射率
n20/D 1.548 (lit.)
沸点
117-118 °C/14 mmHg (lit.)
mp
−1 °C (lit.)
密度
1.155 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
COc1ccc(CCl)cc1
InChI
1S/C8H9ClO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3
InChI key
MOHYOXXOKFQHDC-UHFFFAOYSA-N
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一般描述
4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.
应用
4-Methoxybenzyl chloride was used to benzylate the aniline nitrogen. It was also used in the synthesis of 1-naphthamide and diarymethanes via Suzuki cross-coupling with postassium aryltrifluoroborates.
O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
228.2 °F - closed cup
闪点(°C)
109 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Andrew J Horan et al.
Analytical chemistry, 89(2), 1059-1062 (2017-02-15)
Airborne nanoparticles play a key role in climate effects as well as impacting human health. Their small mass and complex chemical composition represent significant challenges for analysis. This work introduces a new ionization method, droplet assisted inlet ionization (DAII), where
Martin H Bolli et al.
Journal of medicinal chemistry, 47(11), 2776-2795 (2004-05-14)
Since its discovery in 1988 by Yanagisawa et al., endothelin (ET), a potent vasoconstrictor, has been widely implicated in the pathophysiology of cardiovascular, cerebrovascular, and renal diseases. Many research groups have embarked on the discovery and development of ET receptor
Gary A Molander et al.
The Journal of organic chemistry, 71(24), 9198-9202 (2006-11-18)
[reaction: see text] The palladium-catalyzed cross-coupling of potassium aryltrifluoroborates with benzylic halides occurs in good yield with high functional group tolerance. The increased stability of potassium aryltrifluoroborates compared to other boron coupling partners makes this an effective route to functionalized
Synthesis of a potent (?)-4-(2-hydroxyphenyl) analogue of the acromelic acids by dearomatising cyclisation of a lithiated N-p-methoxybenzyl-4-methoxy-1-naphthamide.
Tetrahedron Letters, 42(20), 3407-3410 (2001)
Thompson AS, et al.
Tetrahedron Letters, 36(49), 8937-8940 (1995)
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