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Merck
CN

269190

Sigma-Aldrich

甲基磺酸酐

97%

别名:

甲基磺酰基甲磺酸酯, 甲基磺酸酐, 甲磺酰酐, 甲磺酸酐

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About This Item

线性分子式:
(CH3SO2)2O
CAS号:
分子量:
174.20
Beilstein:
972316
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.3 (vs air)

质量水平

方案

97%

表单

solid

沸点

125 °C/4 mmHg (lit.)

mp

64-67 °C (lit.)

官能团

sulfonic acid

SMILES字符串

CS(=O)(=O)OS(C)(=O)=O

InChI

1S/C2H6O5S2/c1-8(3,4)7-9(2,5)6/h1-2H3

InChI key

IZDROVVXIHRYMH-UHFFFAOYSA-N

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一般描述

甲磺酸酐是一种有机化合物,通常用作制备甲基磺酸盐(甲磺酸盐)的试剂。它还用于使用各种胺前体合成甲磺酰胺。此外,甲磺酸酐和二甲基亚砜的混合物可以用作将伯醇和仲醇氧化为醛和酮的氧化剂。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1A

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Keith Smith et al.
Organic & biomolecular chemistry, 2(21), 3150-3154 (2004-10-27)
Regioselective methanesulfonylation of simple aromatics using methanesulfonic anhydride can be achieved over zeolite catalysts. For example, methanesulfonylation of toluene over various cation-exchanged zeolite beta catalysts affords higher para-selectivity in the synthesis of methyl tolyl sulfone than standard Friedel-Crafts methanesulfonylation utilising
Mohammad Hasani et al.
The journal of physical chemistry. B, 123(8), 1815-1821 (2019-02-20)
Protic ionic liquids (PILs) are made by proton transfer from a Brønsted acid to a base and are of interest for their solvent and electrolyte properties such as high ionic conductivity. Unfortunately, many PILs have been misnamed, because their ionic
Mark C Wilkinson
Organic letters, 13(9), 2232-2235 (2011-03-29)
The utility of methanesulfonic anhydride for promoting the Friedel-Crafts acylation reaction of aryl and alkyl carboxylic acids is disclosed. This reagent allows the preparation of aryl ketones in good yield with minimal waste containing no metallic or halogenated components, clearly

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