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方案
99%
旋光性
[α]25/D +27°, c = 1 in H2O
反应适用性
reaction type: solution phase peptide synthesis
mp
277 °C (dec.) (lit.)
应用
peptide synthesis
SMILES字符串
OC(=O)[C@H]1CCCCN1
InChI
1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m1/s1
InChI key
HXEACLLIILLPRG-RXMQYKEDSA-N
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Kalyanasundaram Subramanian et al.
PloS one, 13(6), e0198990-e0198990 (2018-06-16)
D-amino acid oxidase (DAAO) degrades D-amino acids to produce α-ketoacids, hydrogen peroxide and ammonia. DAAO has often been investigated and engineered for industrial and clinical applications. We combined information from literature with a detailed analysis of the structure to engineer
Hai-Chao Xu et al.
Organic letters, 12(22), 5174-5177 (2010-10-16)
Catalytic intramolecular hydroamination of dithioketene acetals was developed for the synthesis of cyclic amino acid derivatives. Triggered by the addition of a catalytical amount of n-BuLi, the reaction proceeds to give proline and pipecolic acid derivatives in excellent yields and
Wen-Hua Chiou et al.
Organic & biomolecular chemistry, 10(13), 2518-2520 (2012-02-22)
Enantiomeric syntheses of (-)-homopipecolic acid and (-)-pelletierine have been achieved by chiral resolution of tropanol followed by Baeyer-Villiger oxidation. The methodology provides a practical route for the synthesis of optically pure piperidines.
Andrew D Patterson et al.
The Journal of biological chemistry, 286(22), 19511-19522 (2011-04-14)
To enhance understanding of the metabolic indicators of type 2 diabetes mellitus (T2DM) disease pathogenesis and progression, the urinary metabolomes of well characterized rhesus macaques (normal or spontaneously and naturally diabetic) were examined. High-resolution ultra-performance liquid chromatography coupled with the
Santos Fustero et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(12), 3753-3764 (2012-02-16)
The preparation of optically pure quaternary piperidines, both fluorinated and non-fluorinated, has been achieved from a chiral imino lactone derived from (R)-phenylglycinol. In the case of the fluorinated derivatives, the addition of (trifluoromethyl)trimethylsilane (TMSCF(3)) followed by iodoamination and migration of
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