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Merck
CN
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268062

Sigma-Aldrich

D-哌啶酸

99%

别名:

(R)-(+)-2-哌啶甲酸, (R)-哌啶-2-羧酸, D-高脯氨酸

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About This Item

经验公式（希尔记法）:
C6H11NO2
CAS号:
1723-00-8
分子量:
129.16
Beilstein:
81094
EC 号:
217-024-4
MDL编号:
MFCD00064346
UNSPSC代码:
12352209
PubChem化学物质编号:
24856260
NACRES:
NA.22

方案

99%

旋光性

[α]25/D +27°, c = 1 in H2O

反应适用性

reaction type: solution phase peptide synthesis

mp

277 °C (dec.) (lit.)

应用

peptide synthesis

SMILES字符串

OC(=O)[C@H]1CCCCN1

InChI

1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m1/s1

InChI key

HXEACLLIILLPRG-RXMQYKEDSA-N

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
21412AO
07601JS
14703AA
09102MN

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Kalyanasundaram Subramanian et al.
PloS one, 13(6), e0198990-e0198990 (2018-06-16)
D-amino acid oxidase (DAAO) degrades D-amino acids to produce α-ketoacids, hydrogen peroxide and ammonia. DAAO has often been investigated and engineered for industrial and clinical applications. We combined information from literature with a detailed analysis of the structure to engineer
Yi Chai et al.
Chemistry & biology, 17(3), 296-309 (2010-03-27)
The tubulysins are a family of complex peptides with promising cytotoxic activity against multi-drug-resistant tumors. To date, ten tubulysins have been described from the myxobacterial strains Angiococcus disciformis An d48 and Archangium gephyra Ar 315. We report here a third
Hirofumi Inoue et al.
Biological & pharmaceutical bulletin, 34(2), 287-289 (2011-03-19)
A simple and highly sensitive high-performance liquid chromatography method for the determination of pipecolic acid in mouse brain areas was developed. After homogenization of brain and pretreatment with o-phthalaldehyde, the pipecolic acid and (2S,3S)-3-methylpyrrolidine-2-carboxylic acid (internal standard) were derivatized with
Luigi Servillo et al.
Journal of agricultural and food chemistry, 60(1), 315-321 (2012-01-03)
The presence of pipecolic acid and pipecolic acid betaine, also known as homostachydrine, is herein reported for the first time in Citrus genus plants. Homostachydrine was found in fruits, seeds, and leaves of orange, lemon, and bergamot (Citrus bergamia Risso
Rodney A Fernandes et al.
Organic & biomolecular chemistry, 10(38), 7789-7800 (2012-08-23)
A newly developed π-allylpalladium with a (-)-β-pinene framework and an isobutyl side chain catalyzed the enantioselective allylation of imines in good yields and enantioselectivities (20 examples, up to 98% ee). An efficient enantioselective synthesis of the (R)-α-propyl piperonylamine part of
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