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Merck
CN

267317

foil, thickness 0.25 mm, 99.98% trace metals basis

别名:

铼元素

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关于此项目

经验公式(希尔记法):
Re
化学文摘社编号:
分子量:
186.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141737
MDL number:
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InChI

1S/Re

SMILES string

[ReH]

InChI key

WUAPFZMCVAUBPE-UHFFFAOYSA-N

assay

99.98% trace metals basis

form

foil

description

19.3 μΩ-cm, 20°C

thickness

0.25 mm

bp

5596 °C (lit.), 5627 °C (lit.)

mp

3180 °C (lit.)

density

21.02 g/cm3 (lit.)

Quality Level

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General description

铼(Rhenium)是极硬、耐磨损、抗腐蚀的稀有金属,原子序数较大。广泛用于催化领域和喷气发动机合金制备。

Application

铼可用作工作电极,用于电化学 析氢反应。

可用作钼-钛-锆(TZM)合金接头的添加剂,提高 拉伸强度。

也可作为催化剂,用于各种 加氢脱氧反应。

Preparation Note

3.3g = 25×25mm;13.2g = 50×50mm

存储类别

13 - Non Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Cinzia Spagnul et al.
Journal of inorganic biochemistry, 122, 57-65 (2013-03-12)
The synthesis and characterization of two novel water soluble porphyrins with three meso pyridyl rings and one peripheral chelator - either a diethylenetriamine unit (4) or a bipyridyl fragment (8) - for binding to the {(99m)Tc(CO)3}(+) moiety is reported. In
Shalina C Bottorff et al.
Inorganic chemistry, 52(6), 2939-2950 (2013-03-06)
The viability of the Huisgen cycloaddition reaction for clickable radiopharmaceutical probes was explored with an alkyne-functionalized 2-[(pyridin-2-ylmethyl)amino]acetic acid (PMAA) ligand system, 3, and fac-[M(I)(OH2)3(CO)3](+) (M = Re, (99m)Tc). Two synthetic strategies, (1) click, then chelate and (2) chelate, then click
Yanfeng Jiang et al.
Journal of the American Chemical Society, 135(10), 4088-4102 (2013-02-07)
Diiodo Re(I) complexes [ReI2(NO)(PR3)2(L)] (3, L = H2O; 4 , L = H2; R = iPr a, Cy b) were prepared and found to exhibit in the presence of "hydrosilane/B(C6F5)3" co-catalytic systems excellent activities and longevities in the hydrogenation of
Jan Dietrich et al.
Inorganic chemistry, 52(3), 1248-1264 (2013-01-15)
New cationic metallo ligands L1-L3 based on bis(terpyridine) ruthenium(II) complexes decorated with differently substituted 2,2'-bipyridines attached via amide groups (5-NHCO-bpy, 4-CONH-bpy, 5-CONH-bpy) were prepared. Coordination of Re(I)Cl(CO)(3) fragments to the bpy unit gives the corresponding bimetallic Ru~Re complexes 1-3. Hydrogen
Jonathan M Smieja et al.
Inorganic chemistry, 52(5), 2484-2491 (2013-02-20)
Electrocatalytic properties, X-ray crystallographic studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(bpy-tBu)(CO)3Br and [Mn(bpy-tBu)(CO)3(MeCN)](OTf) are reported. Addition of Brönsted acids to CO2-saturated solutions of these Mn complexes and subsequent reduction of the complexes lead to the stable and efficient production of

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