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Merck
CN

265640

Sigma-Aldrich

powder, <150 μm, 99.5% trace metals basis

别名:

Sn

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About This Item

经验公式(希尔记法):
Sn
CAS号:
分子量:
118.71
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99.5% trace metals basis

形式

powder

反应适用性

core: tin
reagent type: catalyst

电阻率

11 μΩ-cm, 20°C

粒径

<150 μm

bp

2270 °C (lit.)

mp

231.9 °C (lit.)

密度

7.310 g/mL at 25 °C (lit.)

SMILES字符串

[Sn]

InChI

1S/Sn

InChI key

ATJFFYVFTNAWJD-UHFFFAOYSA-N

一般描述

锡是一种高效催化剂,用于乳酸缩聚合成聚乳酸。

应用

用HCl还原各种官能团;羰基化合物的立体选择性烯丙基化;原位生成锡烯醇化物用于定向羟醛反应。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Improving lactic acid melt polycondensation: The role of co-catalyst
Marques DS, et al.
Journal of Applied Polymer Science, 128, 2145-2151 (2013)
D B Shpakovsky et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14568-14582 (2012-10-12)
Four new organotin(IV) complexes of bis-(2,6-di-tert-butylphenol)tin(IV) dichloride [(tert-Bu-)(2)(HO-Ph)](2)SnCl(2) (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl-pyrimidine (MPMTH), 2-mercapto-pyridine (PYTH) and 2-mercapto-benzothiazole (MBZTH), of formulae {[(tert-Bu-)(2)(HO-Ph)](2)Sn(PMT)(2)} (2), {[(tert-Bu-)(2)(HO-Ph)](2)Sn(MPMT)(2)} (3), {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(PYT)} (4) and {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(MBZT)} (5), have been synthesized and characterized by elemental
P Olmedo et al.
Environment international, 59, 63-72 (2013-06-25)
Although fish intake has potential health benefits, the presence of metal contamination in seafood has raised public health concerns. In this study, levels of mercury, cadmium, lead, tin and arsenic have been determined in fresh, canned and frozen fish and
A Gassenq et al.
Optics express, 20(25), 27297-27303 (2012-12-25)
A surface-illuminated photoconductive detector based on Ge0.91Sn0.09 quantum wells with Ge barriers grown on a silicon substrate is demonstrated. Photodetection up to 2.2µm is achieved with a responsivity of 0.1 A/W for 5V bias. The spectral absorption characteristics are analyzed
Shiyou Chen et al.
Advanced materials (Deerfield Beach, Fla.), 25(11), 1522-1539 (2013-02-13)
The kesterite-structured semiconductors Cu2ZnSnS4 and Cu2ZnSnSe4 are drawing considerable attention recently as the active layers in earth-abundant low-cost thin-film solar cells. The additional number of elements in these quaternary compounds, relative to binary and ternary semiconductors, results in increased flexibility

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