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应用
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare:
It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
- (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA).
- (±)-Dihydroactinidiolide (a C11-terpenic lactone) via dehydration of key intermediate aeginetolide.
It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
其他说明
含有 β-环柠檬醛
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
An improved synthesis of (?)-dihydroactinidiolide.
Subbaraju GV, et al.
Tetrahedron Letters, 32(37), 4871-4874 (1991)
Improved Synthesis of 2, 6, 6-Trimethyl-1-cyclohexene-1-acetaldehyde, A Key Intermediate for Drimane-Related Sesquiterpenes.
de Jong JC, et al.
Synthetic Communications, 20(4), 589-596 (1990)
Preparation and biological activity of 13-substituted retinoic acids
Wada A, et al.
Bioorganic & Medicinal Chemistry, 12(14), 3931-3942 (2004)
An improved synthesis of (?)-dihydroactinidiolide
Subbaraju GV, et al.
Tetrahedron Letters, 32(37), 4871-4874 (1991)
Improved Synthesis of 2, 6, 6-Trimethyl-1-cyclohexene-1-acetaldehyde, A Key Intermediate for Drimane-Related Sesquiterpenes
de Jong JC, et al.
Synthetic Communications, 20(4), 589-596 (1990)
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