推荐产品
检测方案
97%
形式
liquid
折射率
n20/D 1.454 (lit.)
bp
90-91 °C/19 mmHg (lit.)
密度
0.944 g/mL at 25 °C (lit.)
SMILES字符串
CCOC=CC#N
InChI
1S/C5H7NO/c1-2-7-5-3-4-6/h3,5H,2H2,1H3
InChI key
HUPVIAINOSTNBJ-UHFFFAOYSA-N
一般描述
Heck reaction of 3-ethoxyacrylonitrile with aryl bromides catalyzed by a tetraphosphine/palladium complex has been reported.
应用
3-Ethoxyacrylonitrile has been used in the preparation of (Z)-β-aminoacrylonitrile.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Heck reactions of 2-substituted enol ethers with aryl bromides catalysed by a tetraphosphine/palladium complex.
Battace A, et al.
Tetrahedron Letters, 47(4), 459-462 (2006)
Sundeep Rayat et al.
Chemical research in toxicology, 18(8), 1211-1218 (2005-08-16)
A discussion of nitrosative deamination of cytosine 1 is presented that argues for the formation of 6 by diazotization of 1 to cytosinediazonium ion 2 and its electrostatic complex 3, dediazoniation to 4 <--> 5, and amide-bond cleavage to 6.
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