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形式
liquid
质量水平
反应适用性
core: rhenium
reagent type: catalyst
浓度
75-80 wt. % in H2O
密度
2.16 g/mL at 25 °C
SMILES字符串
O[Re](=O)(=O)=O
InChI
1S/H2O.3O.Re/h1H2;;;;/q;;;;+1/p-1
InChI key
UGSFIVDHFJJCBJ-UHFFFAOYSA-M
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应用
- 高铼酸溶液（HReO4）可用于肟、酰胺和尿素的脱水。
- HReO4还可催化顺醛肟或反醛肟的共沸脱水生成相应的腈。
- 与叔胂结合，可为烯烃与过氧化氢的环氧化提供通用的催化体系。
它还用于制备高导电和超导的合成金属。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Rhenium catalysed epoxidations with hydrogen peroxide: tertiary arsines as effective cocatalysts.
van Vliet, Michiel CA et al.
Journal of the Chemical Society, 114(3), 377-380 (2000)
Alexiane Thevenet et al.
Dalton transactions (Cambridge, England : 2003), 50(5), 1620-1630 (2021-01-21)
The extraction of technetium, present in nitric acid medium as pertechnetate anion, is an issue in solvent extraction processes used to recover uranium and plutonium. In the present study, a complexing agent is added in the aqueous nitric acid solution
Inorg. Synth., 26, 386-386 (1989)
Rhenium (VII) Oxide.
eEROS (Encyclopedia of Reagents for Organic Synthesis), 114(16), 3109-3112 (2001)
Rhenium (VII) oxo complexes as extremely active catalysts in the dehydration of primary amides and aldoximes to nitriles.
Ishihara, Kazuaki et al.
Angewandte Chemie (International Edition in English), 114(16), 3109-3112 (2002)
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