261696
甲基苯基亚砜
≥97%
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关于此项目
线性分子式:
CH3SOC6H5
化学文摘社编号:
分子量:
140.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-781-2
Beilstein/REAXYS Number:
1904976
MDL number:
Assay:
≥97%
Form:
crystals
InChI key
JXTGICXCHWMCPM-UHFFFAOYSA-N
InChI
1S/C7H8OS/c1-9(8)7-5-3-2-4-6-7/h2-6H,1H3
SMILES string
CS(=O)c1ccccc1
assay
≥97%
form
crystals
refractive index
n20/D 1.5775 (lit.)
bp
139-140 °C/14 mmHg (lit.)
Quality Level
mp
26-29 °C (lit.)
functional group
sulfoxide
storage temp.
2-8°C
General description
(R)- 甲基苯基亚砜是一种重要的药物中间体。
Application
甲基苯基亚砜可用于合成：
- 同位素标记的1,3-二噻烷，一种有用的标记合成子
- 奈非那韦，强效HIV蛋白酶抑制剂
- 亚砜亚胺和溶剂-水分配的研究中
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
186.8 °F - closed cup
flash_point_c
86 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
M H Abraham et al.
Journal of pharmaceutical sciences, 83(8), 1085-1100 (1994-08-01)
A general linear solvation energy equation has been used to analyze published partition coefficients in the systems water-octanol (613 solutes), water-hexadecane (370 solutes), water-alkane (200 solutes), and water-cyclohexane (170 solutes). The descriptors used in the equation are R2, an excess
Sadagopan Raghavan et al.
The Journal of organic chemistry, 75(2), 498-501 (2009-12-17)
An asymmetric synthesis of nelfinavir is described starting from acrolein and (S)-methyl phenyl sulfoxide. The key features include (a) stereoselective preparation of a beta-protected amino-gamma,delta-unsaturated sulfoxide by the reaction of an alpha-sulfinyl carbanion with an unsaturated t-butyl sulfinylimine, (b) stereoselective
Aldrichimica Acta, 18, 3-3 (1985)
Nathalie Sauvonnet et al.
The Journal of cell biology, 168(1), 155-163 (2004-12-30)
Endocytosis is critical for many cellular functions. We show that endocytosis of the common gammac cytokine receptor is clathrin independent by using a dominant-negative mutant of Eps15 or RNA interference to knock down clathrin heavy chain. This pathway is synaptojanin
Dandan Rao et al.
Water research, 188, 116481-116481 (2020-10-12)
Although permanganate activation by sodium sulfite (Mn(VII)/Na2SO3) has shown great potential for rapid abatement of organic contaminants, the limited reactivity under alkaline conditions and undesirable Mn residual may prevent its widespread application. To solve these challenges, calcium sulfite (CaSO3) was
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