261610
溴化氰 溶液
5.0 M in acetonitrile
别名:
Bromine cyanide, Bromine monocyanide, Bromocyanide, Bromocyanogen, Carbononitridic bromide, Cyanic bromide, Cyanobromide, Cyanogen monobromide
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所有图片(1)
About This Item
线性分子式:
BrCN
CAS号:
分子量:
105.92
Beilstein:
1697296
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
形式
liquid
质量水平
浓度
5.0 M in acetonitrile
溶解性
alcohol: freely soluble(lit.)
diethyl ether: freely soluble(lit.)
water: freely soluble(lit.)
密度
1.093 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
BrC#N
InChI
1S/CBrN/c2-1-3
InChI key
ATDGTVJJHBUTRL-UHFFFAOYSA-N
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一般描述
Cyanogen bromide solution induces template-guided condensation of oligonucleotides only in the presence of N-substituted morpholines. Mechanism of the phosphomonoester group activation by cyanogen bromide in N-substituted morpholine buffers has been investigated.
应用
Cyanogen bromide is a general reagent used to cleave carbon-heteroatom bonds. It is used in the synthesis of organocyanamides from corresponding tertiary amines, which is popularly known as von Braun reaction. CNBr solution is widely used in protein immobilization and cleavage.
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
补充剂危害
WGK
WGK 3
闪点(°F)
42.8 °F
闪点(°C)
6 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Wen Qian et al.
Scientific reports, 10(1), 6470-6470 (2020-04-15)
The conjugation of polysaccharides with an effective carrier protein is critical for the development of effective bacterial polysaccharide vaccines. Therefore, the identification and optimization of carrier proteins to induce an effective immune response is necessary for developing a combined vaccine.
Cyanogen Bromide.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Bromalkylierte aromatische Amine. II. Mitteilung.
v Braun J, et al.
Ber. Deutsch. Chem. Ges., 51, 273-282 (1918)
Immobilization of lipases on hydrophobic supports involves the open form of the enzyme.
Manoel EA, et al.
Enz. Microbiol. Technol., 71, 53-57 (2015)
Z A Shabarova et al.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 27(5-6), 555-566 (2001-09-07)
Cyanogen bromide has been found to induce the template-guided condensation of oligonucleotides only in the presence of N-substituted morpholines. Based on 31P, 1H and 13C NMR spectroscopy data, the mechanism of the phosphomonoester group activation by cyanogen bromide in N-substituted
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