261610
溴化氰 溶液
5.0 M in acetonitrile
别名:
Bromine cyanide, Bromine monocyanide, Bromocyanide, Bromocyanogen, Carbononitridic bromide, Cyanic bromide, Cyanobromide, Cyanogen monobromide
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关于此项目
线性分子式:
BrCN
化学文摘社编号:
分子量:
105.92
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1697296
Form:
liquid
InChI
1S/CBrN/c2-1-3
SMILES string
BrC#N
InChI key
ATDGTVJJHBUTRL-UHFFFAOYSA-N
form
liquid
concentration
5.0 M in acetonitrile
solubility
alcohol: freely soluble(lit.), diethyl ether: freely soluble(lit.), water: freely soluble(lit.)
density
1.093 g/mL at 25 °C
functional group
bromo
storage temp.
2-8°C
Quality Level
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General description
Cyanogen bromide solution induces template-guided condensation of oligonucleotides only in the presence of N-substituted morpholines. Mechanism of the phosphomonoester group activation by cyanogen bromide in N-substituted morpholine buffers has been investigated.
Application
Cyanogen bromide is a general reagent used to cleave carbon-heteroatom bonds. It is used in the synthesis of organocyanamides from corresponding tertiary amines, which is popularly known as von Braun reaction. CNBr solution is widely used in protein immobilization and cleavage.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Cyanogen Bromide.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Wen Qian et al.
Scientific reports, 10(1), 6470-6470 (2020-04-15)
The conjugation of polysaccharides with an effective carrier protein is critical for the development of effective bacterial polysaccharide vaccines. Therefore, the identification and optimization of carrier proteins to induce an effective immune response is necessary for developing a combined vaccine.
Z A Shabarova et al.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 27(5-6), 555-566 (2001-09-07)
Cyanogen bromide has been found to induce the template-guided condensation of oligonucleotides only in the presence of N-substituted morpholines. Based on 31P, 1H and 13C NMR spectroscopy data, the mechanism of the phosphomonoester group activation by cyanogen bromide in N-substituted
Immobilization of lipases on hydrophobic supports involves the open form of the enzyme.
Manoel EA, et al.
Enz. Microbiol. Technol., 71, 53-57 (2015)
Bromalkylierte aromatische Amine. II. Mitteilung.
v Braun J, et al.
Ber. Deutsch. Chem. Ges., 51, 273-282 (1918)
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