质量水平
检测方案
99.9% trace rare earth metals basis
形式
powder
电阻率
50.5 μΩ-cm, 0°C
bp
2836 °C (lit.)
mp
1540 °C (lit.)
密度
2.99 g/mL at 25 °C (lit.)
SMILES字符串
[Sc]
InChI
1S/Sc
InChI key
SIXSYDAISGFNSX-UHFFFAOYSA-N
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应用
用于不常见簇合物 Sc19Br28Z4（Z = Mn、Fe、Ru 或 Os）的固态合成。这些簇合物由于其结构和磁特性而倍受关注。
Andrea Olmos et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4894-4901 (2012-03-15)
This study demonstrates the first zeolite-catalyzed synthesis of piperidine derivatives, including peptidomimetics and indoloquinolizidine alkaloids. The approach developed utilizes a highly effective one-pot reaction cascade, through imine formation and imino-Diels-Alder reactions, promoted by scandium-loaded zeolites as a heterogeneous catalyst. The
Jacob S Kanady et al.
Journal of the American Chemical Society, 135(3), 1073-1082 (2012-12-18)
The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable
Asymmetric synthesis of β-amino nitriles through a Sc(III)-catalyzed three-component Mannich reaction of silyl ketene imines.
Jiannan Zhao et al.
Angewandte Chemie (International ed. in English), 52(12), 3473-3477 (2013-02-14)
Marek Pruszyński et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(6), 974-979 (2012-04-03)
The positron-emitting radionuclide (44)Sc with a half-life of 3.97 h and a β(+) branching of 94.3% is of potential interest for clinical PET. As so far it is available from a (44)Ti/(44)Sc generator in Mainz, where long-lived (44)Ti decays to
Vincent Tran et al.
Organic letters, 14(23), 6100-6103 (2012-11-23)
Treatment of ynol ether-tethered dialkyl acetals with catalytic quantities of scandium triflate in CH(3)CN gives rise to five-, six-, and seven-membered alkoxycycloalkene carboxylates in good to excellent yields. Tri- and tetrasubstituted carbocyclic and heterocyclic alkenes may be formed by this
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