258849
1,6-庚二烯
99%
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关于此项目
线性分子式:
CH2=CH(CH2)3CH=CH2
化学文摘社编号:
分子量:
96.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1731760
产品名称
1,6-庚二烯, 99%
InChI
1S/C7H12/c1-3-5-7-6-4-2/h3-4H,1-2,5-7H2
SMILES string
C=CCCCC=C
InChI key
GEAWFZNTIFJMHR-UHFFFAOYSA-N
assay
99%
form
liquid
refractive index
n20/D 1.414 (lit.)
bp
89-90 °C (lit.)
mp
−129.4-−129 °C (lit.)
density
0.714 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
1,6-Heptadiene has been used as a starting reagent in asymmetric synthesis of all stereoisomers of 6-methylpipecolic acids.
General description
Highly stereoselective and regiospecific living coordination polymerization of 1,6-heptadiene has been used to generate a spectrum of different physical forms of poly(1,3-methylenecyclohexane).
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
15.8 °F - closed cup
flash_point_c
-9 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
H Takahata et al.
Amino acids, 24(3), 267-272 (2003-04-23)
Asymmetric synthesis of all four stereoisomers of 6-methylpipecolic acids with high enantiomeric purity via iterative AD reaction, starting from 1,6-heptadiene, has been described.
Kaitlyn E Crawford et al.
Journal of the American Chemical Society, 135(24), 8778-8781 (2013-05-23)
External control over the rate of dynamic methyl group exchange between configurationally stable active species and configurationally unstable dormant species with respect to chain-growth propagation within a highly stereoselective and regiospecific living coordination polymerization of 1,6-heptadiene has been used to
Roda Seseogullari-Dirihan et al.
Dental materials journal, 37(3), 445-452 (2018-03-02)
The aim of this study was to evaluate the effect of curcuminoids on the dentin endogenous protease activity. Demineralized dentin were pretreated with 50 or 100 µM of three different curcuminoids for 60 s and incubated up to 3 months.
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