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Merck
CN

257621

2,2-二(4-叔辛基苯基)-1-苦基肼基,自由基

别名:

2,2-二(4-辛基苯基)-1-苦基肼基, 2,2-双[4-(1,1,3,3-四甲基丁基)苯基]-1-(2,4,6-三硝基苯基)肼基, DPPH

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关于此项目

经验公式(希尔记法):
C34H44N5O6
化学文摘社编号:
分子量:
618.74
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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表单

solid

质量水平

mp

171 °C (dec.) (lit.)

λmax

531 nm

官能团

nitro

储存温度

2-8°C

SMILES字符串

CC(C)(C)CC(C)(C)c1ccc(cc1)N([N]c2c(cc(cc2[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)c3ccc(cc3)C(C)(C)CC(C)(C)C

InChI

1S/C34H44N5O6/c1-31(2,3)21-33(7,8)23-11-15-25(16-12-23)36(26-17-13-24(14-18-26)34(9,10)22-32(4,5)6)35-30-28(38(42)43)19-27(37(40)41)20-29(30)39(44)45/h11-20H,21-22H2,1-10H3

InChI key

CLOCMRDQPYXVKP-UHFFFAOYSA-N

一般描述

2,2-二(4-叔辛基苯基)-1-苦基肼基(DPPH)是一种“稳定”的自由基,因为它的保质期长,并可在一般的实验室条件下合成和储存。

应用

2,2-二(4-叔辛基苯基)-1-苦基肼基(DPPH)可作为电子顺磁共振光谱法(EPR)的校准标准品,以及聚合物的自由基清除剂。也可作为“DPPH比色法”的有效试剂,用于检测各种化合物(大部分为酚类)的自由基清除能力。DPPH与抗氧化剂反应后,颜色从深紫色变成浅黄色,通过分光光度法可测定抗氧化剂活性。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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Zeynep Akar et al.
Journal of enzyme inhibition and medicinal chemistry, 32(1), 640-647 (2017-03-07)
2,2-Diphenyl-1-picrylhydrazyl (DPPH•) radical scavenging, the most commonly used antioxidant method with more than seventeen thousand articles cited, is very practical; however, as with most assays, it has the major disadvantage of dependence on a spectrophotometer. To overcome this drawback, the
DPPH (2, 2-di (4-tert-octylphenyl)-1-picrylhydrazyl) radical scavenging mixed-mode colorimetric assay (s)
Measurement of Antioxidant Activity and Capacity: Recent Trends and Applications, 141-164 (2017)
Christian Galasso et al.
International journal of molecular sciences, 21(22) (2020-11-22)
The antioxidant activity of natural compounds consists in their ability to modulate gene and protein expression, thus inducing an integrated cell protective response and repair processes against oxidative stress. New screening tools and methodologies are crucial for the actual requirement
Ramona Figat et al.
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Huanhuan Xu et al.
Frontiers in cell and developmental biology, 8, 822-822 (2020-10-06)
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